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科研机构
长春应用化学研究所 [1]
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期刊论文 [1]
发表日期
2014 [1]
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Effect of Zn doping on the hydrogenolysis of glycerol over ZnNiAl catalyst
期刊论文
journal of molecular catalysis a-chemical, 2014, 卷号: 395, 页码: 1-6
Li, Xiaoru
;
Zhang, Chao
;
Cheng, Haiyang
;
He,Limin
;
Lin,Weiwei
;
Yu,Yancun
;
Zhao,Fengyu
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提交时间:2015/10/20
Nickel based catalyst is of interest in the industrial catalytic processes
and it is always modified by doping a second element to improve its catalytic properties. Understanding the role of dopant is extremely helpful in tailoring the active centers. In this work
Zn could induce a significant improvement of the catalytic performance of NiAl for the hydrogenolysis of glycerol. The Zn doped ZnNiAl catalysts exhibited high activity and the improved selectivity to 1
2-propanediol
it was about 2 times higher than the original ones. The ZnNi alloy formed in ZnNiAl was responsible for the noticeable catalytic performance. They preferred to coordinate with the end hydroxyl group of glycerol
promoted the cleavage of C-O bond in glycerol
and resulted in the dominant formation of 1
2-propanediol. The findings described here will provide a useful knowledge for rational design of nickel-based catalysts
as well as reveal a new reaction model for the hydrogenolysis of glycerol. (C) 2014 Elsevier B.V. All rights reserved.
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