The research of crystal structure and electrical properties of a new electrolyte material: Scandia and Holmia stabilized Zirconia | |
Tao, Jingchao1; Hao, Yong2; Wang, Jun1 | |
刊名 | JOURNAL OF THE CERAMIC SOCIETY OF JAPAN |
2013-03-01 | |
卷号 | 121期号:1411页码:317-325 |
关键词 | Scandia and Holmia stabilized Zirconia Oxygen vacancy Specific grain boundary Space charge potential |
英文摘要 | Weakly agglomerated nano-crystalline Ho2O3 and Sc2O3 stabilized ZrO2 (HoScSZ) powders are prepared by the hydrothermal method. Dense HoScSZ ceramic pellets are fabricated by isostatically pressing the powders then sintering at 1350 degrees C for 2 h. All the HoScSZ samples are cubic phase verified by X-ray diffraction. 7 mol % Sc2O3 + 1 mol % Ho2O3 stabilized zirconia (7Sc1HoSZ) is verified by impedance spectroscopy possessing the higher conductivity than that of 8 mol % Sc2O3 stabilized zirconia (8ScSZ). Space charge potential and specific grain boundary conductivity are calculated and fitted under the circumstance that the grain boundary is free of any amorphous phase which is verified by high resolution transmission electron microscopy. With the increase of the doping content of Ho2O3, the specific grain boundary conductivity and space charge potential decrease, while oxygen vacancy concentration increases. (C)2013 The Ceramic Society of Japan. All rights reserved. |
WOS标题词 | Science & Technology ; Technology |
类目[WOS] | Materials Science, Ceramics |
研究领域[WOS] | Materials Science |
关键词[WOS] | GRAIN-BOUNDARY RESISTIVITY ; OXIDE FUEL-CELL ; POLYCRYSTALLINE MATERIALS ; CONDUCTIVITY ; SYSTEM ; MICROSTRUCTURE |
收录类别 | SCI |
语种 | 英语 |
WOS记录号 | WOS:000316771200014 |
内容类型 | 期刊论文 |
源URL | [http://ir.etp.ac.cn/handle/311046/98851] |
专题 | 工程热物理研究所_中国科学院工程热物理所(论文库)_期刊论文(SCI) |
作者单位 | 1.Shanghai Jiao Tong Univ, State Key Lab Met Matrix Composites, Shanghai 200240, Peoples R China 2.Chinese Acad Sci, Inst Engn Thermophys, Beijing 100190, Peoples R China |
推荐引用方式 GB/T 7714 | Tao, Jingchao,Hao, Yong,Wang, Jun. The research of crystal structure and electrical properties of a new electrolyte material: Scandia and Holmia stabilized Zirconia[J]. JOURNAL OF THE CERAMIC SOCIETY OF JAPAN,2013,121(1411):317-325. |
APA | Tao, Jingchao,Hao, Yong,&Wang, Jun.(2013).The research of crystal structure and electrical properties of a new electrolyte material: Scandia and Holmia stabilized Zirconia.JOURNAL OF THE CERAMIC SOCIETY OF JAPAN,121(1411),317-325. |
MLA | Tao, Jingchao,et al."The research of crystal structure and electrical properties of a new electrolyte material: Scandia and Holmia stabilized Zirconia".JOURNAL OF THE CERAMIC SOCIETY OF JAPAN 121.1411(2013):317-325. |
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