Adsorption of nitrophenol compounds from aqueous solution by cross-linked starch-based polymers | |
Zhang Q.; Okoli, C. P.; Wang, L. Q.; Liang, T. | |
2015 | |
关键词 | Cross-linked starch polymers Nitrophenols Adsorption beta-cyclodextrin photocatalytic degradation waste-water removal ions sorption phenol starch/acrylonitrile thermodynamics adsorbents |
英文摘要 | Two kinds of cross-linked starch polymers were synthesized and used as adsorbent materials for the adsorption of o-nitrophenol (o-NP), p-nitrophenol (p-NP), 2,4-dinitrophenol (2,4-DNP) and 2-s-butyl-4,6-dinitrophenol (DNBP) from aqueous solutions. Results from adsorption experiments showed that the polymer 1 prepared by 4,4 '-methylene-bis-phenyldiisocyanate (MDI) as cross-linking agent exhibited higher adsorption behaviors than that of the polymer 2 prepared by hexamethylene diisocyanate (HMDI). Equilibrium and thermodynamic of four nitrophenols on polymer 1 were further studied. Analyzed experimental data showed that the Freundlich model fitted the isotherm data better than the Langmuir model of the four nitrophenols onto polymer 1. The thermodynamics for the adsorption of the nitrophenols on polymer 1 were estimated in the range of 303-333 K. It has been found that the values of Gibbs free energy (Delta G) became more negative with decreasing temperature, which indicated that the adsorption process was more favorable at low temperature. |
出处 | Desalination and Water Treatment |
卷 | 55 |
期 | 6 |
页 | 1575-1585 |
收录类别 | SCI |
语种 | 英语 |
ISSN号 | 1944-3994 |
内容类型 | SCI/SSCI论文 |
源URL | [http://ir.igsnrr.ac.cn/handle/311030/38527] |
专题 | 地理科学与资源研究所_历年回溯文献 |
推荐引用方式 GB/T 7714 | Zhang Q.,Okoli, C. P.,Wang, L. Q.,et al. Adsorption of nitrophenol compounds from aqueous solution by cross-linked starch-based polymers. 2015. |
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