Adsorption of nitrophenol compounds from aqueous solution by cross-linked starch-based polymers
Zhang Q.; Okoli, C. P.; Wang, L. Q.; Liang, T.
2015
关键词Cross-linked starch polymers Nitrophenols Adsorption beta-cyclodextrin photocatalytic degradation waste-water removal ions sorption phenol starch/acrylonitrile thermodynamics adsorbents
英文摘要Two kinds of cross-linked starch polymers were synthesized and used as adsorbent materials for the adsorption of o-nitrophenol (o-NP), p-nitrophenol (p-NP), 2,4-dinitrophenol (2,4-DNP) and 2-s-butyl-4,6-dinitrophenol (DNBP) from aqueous solutions. Results from adsorption experiments showed that the polymer 1 prepared by 4,4 '-methylene-bis-phenyldiisocyanate (MDI) as cross-linking agent exhibited higher adsorption behaviors than that of the polymer 2 prepared by hexamethylene diisocyanate (HMDI). Equilibrium and thermodynamic of four nitrophenols on polymer 1 were further studied. Analyzed experimental data showed that the Freundlich model fitted the isotherm data better than the Langmuir model of the four nitrophenols onto polymer 1. The thermodynamics for the adsorption of the nitrophenols on polymer 1 were estimated in the range of 303-333 K. It has been found that the values of Gibbs free energy (Delta G) became more negative with decreasing temperature, which indicated that the adsorption process was more favorable at low temperature.
出处Desalination and Water Treatment
55
6
1575-1585
收录类别SCI
语种英语
ISSN号1944-3994
内容类型SCI/SSCI论文
源URL[http://ir.igsnrr.ac.cn/handle/311030/38527]  
专题地理科学与资源研究所_历年回溯文献
推荐引用方式
GB/T 7714
Zhang Q.,Okoli, C. P.,Wang, L. Q.,et al. Adsorption of nitrophenol compounds from aqueous solution by cross-linked starch-based polymers. 2015.
个性服务
查看访问统计
相关权益政策
暂无数据
收藏/分享
所有评论 (0)
暂无评论
 

除非特别说明,本系统中所有内容都受版权保护,并保留所有权利。


©版权所有 ©2017 CSpace - Powered by CSpace