Optical properties of a binuclear neodymium complex in phosphorus oxychloride for liquid laser

CORC > 西安光学精密机械研究所 > 中国科学院西安光学精密机械研究所 > 先进光电与生物材料研发中心

	Optical properties of a binuclear neodymium complex in phosphorus oxychloride for liquid laser
	Zhang, Guofang 1; She, Jiangbo2 ; Han, Kai 1; Nie, Rongzhi 2; Li, Dongdong 3; Peng, Bo2
刊名	optical materials
	2015-11-01
卷号	49 页码:343-347
关键词	Crystal structure Optical property Judd-Ofelt theory Liquid laser Emission cross-section
英文摘要	a novel binuclear neodymium complex nd(cf3coo)(3)center dot(ph3po)(2) (ph3po: triphenylphosphine oxide) with high stimulated emission cross-section was presented. the molecular structure of the complex was characterized by single-crystal x-ray diffraction. the optical properties of the complex in liquid medium were studied. from the absorption and luminescence spectra, the judd-ofelt parameters of nd (cf3coo)(3)center dot(ph3po)(2) in phosphorus oxychloride were obtained. based on the crystal structure, the effects of crystal field and bonding valence properties on three intensity parameters omega(t)(t = 2, 4, 6) and emission cross-section were analyzed in detail. the emission cross-section of e-4(3/2) -> i-4(11/2) fluorescence transition (2.78 x 10(-2) cm(2)) of the new neodymium compound was higher than those of other nd(iii) complexes and even comparable with some laser glasses. (c) 2015 elsevier bm. all rights reserved.
学科主题	materials science, multidisciplinary ; optics
WOS标题词	science & technology ; technology ; physical sciences
类目[WOS]	materials science, multidisciplinary ; optics
研究领域[WOS]	materials science ; optics
关键词[WOS]	rare-earth ions ; transition-probabilities ; lanthanide complexes ; stimulated-emission ; borate glasses ; nd3+ ions ; luminescent ; spectroscopy ; intensities ; absorption
收录类别	SCI ; EI
语种	英语
WOS记录号	WOS:000364255100054
内容类型	期刊论文
源URL	[http://ir.opt.ac.cn/handle/181661/27264]
专题	西安光学精密机械研究所_先进光电与生物材料研发中心
作者单位	1.Shaanxi Normal Univ, Sch Chem & Chem Engn, MOE, Key Lab Appl Surface & Colloid Chem, Xian 710062, Peoples R China 2.Chinese Acad Sci, State Key Lab Transient Opt & Photon, Xian Inst Opt & Precis Mech, Xian 710119, Shaanxi, Peoples R China 3.Xian Univ Post & Telecommun, Sch Elect Engn, Xian 710121, Shaanxi, Peoples R China
推荐引用方式 GB/T 7714	Zhang, Guofang,She, Jiangbo,Han, Kai,et al. Optical properties of a binuclear neodymium complex in phosphorus oxychloride for liquid laser[J]. optical materials,2015,49:343-347.
APA	Zhang, Guofang,She, Jiangbo,Han, Kai,Nie, Rongzhi,Li, Dongdong,&Peng, Bo.(2015).Optical properties of a binuclear neodymium complex in phosphorus oxychloride for liquid laser.optical materials,49,343-347.
MLA	Zhang, Guofang,et al."Optical properties of a binuclear neodymium complex in phosphorus oxychloride for liquid laser".optical materials 49(2015):343-347.