Synthesis, crystal structure and EPR spectra of cis-dioxo-molybdenum(V) with catechol ligand

CORC > 武汉物理与数学研究所 > 中国科学院武汉物理与数学研究所 > 2011年以前论文发表（包括2011年）

	Synthesis, crystal structure and EPR spectra of cis-dioxo-molybdenum(V) with catechol ligand
	Lu, XM ; Liu, SC ; Mao, X ; Bu, XH
刊名	JOURNAL OF MOLECULAR STRUCTURE
	2001-05-02
卷号	562 期号:1-3 页码:89-94
关键词	cis-dioxo-molybdenum(V) complex anion pseudo-octahedra catechol X-ray crystallography EPR spectra
英文摘要	The cis-dioxo-molybdenum(V) complex anion [(MoO2)-O-(V)(C6H4O2)(2)](3-) was obtained by the reaction of tetra-butyl ammonium beta -octamolybdate with catechol and ethylenediamine in the mixed solvent of CH3OH and CH3CN, and characterized by IR, NM, UV, EPR spectroscopy and X-ray diffraction with its discrete (NH2CH2CH2NH3)(+) cations. The determination of single crystal X-ray analysis revealed that the metal center exhibits distorted octahedral co-ordination with cis dioxo catechol. The result of essentially the same of EPR spectra shown by the complex and flavoenzyme suggests that the title complex anion and flavoenzyme have related structure feature. (C) 2001 Elsevier Science B.V. All rights reserved.
WOS标题词	Science & Technology ; Physical Sciences
类目[WOS]	Chemistry, Physical
研究领域[WOS]	Chemistry
关键词[WOS]	DMSO REDUCTASE ; ACTIVE-SITES ; COMPLEXES ; TUNGSTOENZYMES
收录类别	SCI
语种	英语
WOS记录号	WOS:000168080900010
公开日期	2015-12-08
内容类型	期刊论文
源URL	[http://ir.wipm.ac.cn/handle/112942/8621]
专题	武汉物理与数学研究所_2011年以前论文发表（包括2011年）
作者单位	1.Capital Normal Univ, Dept Chem, Beijing 100037, Peoples R China 2.Chinese Acad Sci, Wuhan Inst Phys & Math, Wuhan 430071, Peoples R China 3.Nankai Univ, Dept Chem, Tianjin 300071, Peoples R China
推荐引用方式 GB/T 7714	Lu, XM,Liu, SC,Mao, X,et al. Synthesis, crystal structure and EPR spectra of cis-dioxo-molybdenum(V) with catechol ligand[J]. JOURNAL OF MOLECULAR STRUCTURE,2001,562(1-3):89-94.
APA	Lu, XM,Liu, SC,Mao, X,&Bu, XH.(2001).Synthesis, crystal structure and EPR spectra of cis-dioxo-molybdenum(V) with catechol ligand.JOURNAL OF MOLECULAR STRUCTURE,562(1-3),89-94.
MLA	Lu, XM,et al."Synthesis, crystal structure and EPR spectra of cis-dioxo-molybdenum(V) with catechol ligand".JOURNAL OF MOLECULAR STRUCTURE 562.1-3(2001):89-94.