New mineralization agents for the synthesis of MCM-41

CORC > 武汉物理与数学研究所 > 中国科学院武汉物理与数学研究所 > 2011年以前论文发表（包括2011年）

	New mineralization agents for the synthesis of MCM-41
	Lin, WY ; Cai, Q ; Pang, WQ ; Yue, Y ; Zou, BS
刊名	MICROPOROUS AND MESOPOROUS MATERIALS
	1999-12-15
卷号	33 期号:1-3 页码:187-196
关键词	MCM-41 mineralization agent molecular sieve
英文摘要	Silicate and aluminosilicate MCM-41 molecular sieves have been synthesized in the presence of various new mineralization agents, such as methylamine, dimethylamine, ethylamine and diethylamine. The products were characterized with a series of techniques. XRD, TEM and nitrogen adsorption-desorption measurements suggest that the products possess highly ordered structures. Si-29 NMR results show that the resultant mesophase frameworks are condensed with a higher degree than those of products prepared with NaOH as the mineralization agent. These alkalimetal-free synthesis media offer a simple and effective method for the direct preparation of high quality H-type aluminosilicate MCM-41, as shown by XRD, Al-27 NMR and NH, TPD results. Both the pure silica and the aluminum-containing samples exhibit excellent thermal tin air up to 1373 K) and hydrothermal stability tin hot water of 353 K, 48 h for the former and 72 h for the later). The formation of the high quality MCM-41 material is discussed in terms of a buffer effect of the synthesis media, which is due to the presence of the new mineralization agents. The evidence was obtained by monitoring the pH values of the synthesis. (C) 1999 Elsevier Science B.V. All rights, reserved.
WOS标题词	Science & Technology ; Physical Sciences ; Technology
类目[WOS]	Chemistry, Applied ; Chemistry, Physical ; Nanoscience & Nanotechnology ; Materials Science, Multidisciplinary
研究领域[WOS]	Chemistry ; Science & Technology - Other Topics ; Materials Science
关键词[WOS]	MESOPOROUS MOLECULAR-SIEVES ; HYDROTHERMAL STABILITY ; SILICA ; SURFACTANTS ; MECHANISM ; CATALYSTS ; ROUTE
收录类别	SCI
语种	英语
WOS记录号	WOS:000083959100014
公开日期	2015-12-01
内容类型	期刊论文
源URL	[http://ir.wipm.ac.cn/handle/112942/8379]
专题	武汉物理与数学研究所_2011年以前论文发表（包括2011年）
作者单位	1.Jilin Univ, Dept Chem, Key Lab Inorgan Synth & Preparat Chem, Changchun 130023, Peoples R China 2.Chinese Acad Sci, Wuhan Inst Phys, Wuhan 430071, Peoples R China 3.Inst Yanshan Petr & Chem Co, Beijing 102550, Peoples R China
推荐引用方式 GB/T 7714	Lin, WY,Cai, Q,Pang, WQ,et al. New mineralization agents for the synthesis of MCM-41[J]. MICROPOROUS AND MESOPOROUS MATERIALS,1999,33(1-3):187-196.
APA	Lin, WY,Cai, Q,Pang, WQ,Yue, Y,&Zou, BS.(1999).New mineralization agents for the synthesis of MCM-41.MICROPOROUS AND MESOPOROUS MATERIALS,33(1-3),187-196.
MLA	Lin, WY,et al."New mineralization agents for the synthesis of MCM-41".MICROPOROUS AND MESOPOROUS MATERIALS 33.1-3(1999):187-196.