TiO(2)/SBA-15 photocatalysts synthesized through the surface acidolysis of Ti(O(n)Bu)(4) on carboxyl-modified SBA-15 | |
Zhang, Shucui1,3; Jiang, Dong1; Tang, Tao1,3; Li, Junhua1,3; Xu, Yao1; Shen, Wanling2,3; Xu, Jun2; Deng, Feng2 | |
刊名 | CATALYSIS TODAY |
2010-12-22 | |
卷号 | 158期号:3-4页码:329-335 |
关键词 | TiO(2) Mesoporous materials Acidolysis Photocatalysis |
英文摘要 | Based on an acidolysis reaction between titanium n-butoxide and carboxyl (COOH) groups, serial highly dispersed TiO(2) photocatalysts were successfully synthesized on COOH-modified mesoporous SBA-15 material. Even after calcined at 550 degrees C to improve the crystallization, the TiO(2)/SBA-15 products possessed high surface area above 400 m(2) g(-1) that should be attributed to the high porosity of mesoporous SBA-15 and the highly uniform COOH group distribution in mesopores. HRTEM images revealed that TiO(2) nanocrystals dispersed well on the surface of SBA-15. The pore channels were partly blocked by TiO(2) nanocrystals, resulting in a bimodal pore size distribution in TiO(2)/SBA-15 compared with SBA-15. XRD and Raman results disclosed the exclusive anatase phase of TiO(2) in the photocatalysts. With adjusting the molar ratio of COOH to TB, the TiO(2)/SBA-15 products displayed different photocatalytic performance using Rhodamine B as probe under UV light. (C) 2010 Elsevier B.V. All rights reserved. |
WOS标题词 | Science & Technology ; Physical Sciences ; Technology |
类目[WOS] | Chemistry, Applied ; Chemistry, Physical ; Engineering, Chemical |
研究领域[WOS] | Chemistry ; Engineering |
关键词[WOS] | AQUEOUS TIO2 SUSPENSIONS ; MESOPOROUS SILICA ; TIO2-BASED PHOTOCATALYSTS ; ORGANIC-MOLECULES ; RAMAN-SPECTRUM ; ANATASE TIO2 ; THIN-FILMS ; TITANIUM ; NANOPARTICLES ; LUMINESCENCE |
收录类别 | SCI |
语种 | 英语 |
WOS记录号 | WOS:000284583300023 |
公开日期 | 2015-12-01 |
内容类型 | 期刊论文 |
源URL | [http://ir.wipm.ac.cn/handle/112942/8198] |
专题 | 武汉物理与数学研究所_2011年以前论文发表(包括2011年) |
作者单位 | 1.Chinese Acad Sci, State Key Lab Coal Convers, Inst Coal Chem, Taiyuan 030001, Shanxi, Peoples R China 2.Chinese Acad Sci, State Key Lab Magnet Resonance & Atom & Mol Phys, Wuhan Inst Phys & Math, Wuhan 430071, Peoples R China 3.Chinese Acad Sci, Grad Univ, Beijing 100049, Peoples R China |
推荐引用方式 GB/T 7714 | Zhang, Shucui,Jiang, Dong,Tang, Tao,et al. TiO(2)/SBA-15 photocatalysts synthesized through the surface acidolysis of Ti(O(n)Bu)(4) on carboxyl-modified SBA-15[J]. CATALYSIS TODAY,2010,158(3-4):329-335. |
APA | Zhang, Shucui.,Jiang, Dong.,Tang, Tao.,Li, Junhua.,Xu, Yao.,...&Deng, Feng.(2010).TiO(2)/SBA-15 photocatalysts synthesized through the surface acidolysis of Ti(O(n)Bu)(4) on carboxyl-modified SBA-15.CATALYSIS TODAY,158(3-4),329-335. |
MLA | Zhang, Shucui,et al."TiO(2)/SBA-15 photocatalysts synthesized through the surface acidolysis of Ti(O(n)Bu)(4) on carboxyl-modified SBA-15".CATALYSIS TODAY 158.3-4(2010):329-335. |
个性服务 |
查看访问统计 |
相关权益政策 |
暂无数据 |
收藏/分享 |
除非特别说明,本系统中所有内容都受版权保护,并保留所有权利。
修改评论