Photoelectron Imaging of AgOCH3- and Ag-(CH3OH)(x) (x=1, 2)

	Photoelectron Imaging of AgOCH3- and Ag-(CH3OH)(x) (x=1, 2)
	Chi, Chao-xian 2; Xie, Hua 1; Cong, Ran 1; Tang, Zi-chao 1; Zhou, Ming-fei 2
刊名	chinese journal of chemical physics
	2011-10-01
卷号	24 期号:5 页码:557-562
关键词	Silver methanol complex Solvation Photoelectron imaging Density functional calculation
英文摘要	the agoch3- and ag-(ch3oh)(x) (x=1, 2) anions are studied by photoelectron imaging as well as ab initio calculations. the adiabatic and vertical detachment energies (ade and vde) of agoch3- are determined as 1.29(2) and 1.34(2) ev, respectively, from the vibrational resolved photoelectron spectrum. the ag-(ch3oh)1,2 anionic complexes are characterized as metal atomic anion solvated by the ch3oh molecules with the electron mainly localized on the metal. the photoelectron spectra of ag-(ch3oh)(x) (x=0, 1, 2) show a gradual increase in vde with increasing x, due to the solvent stabilization. evidence for the methanol-methanol hydrogen bonding interactions appears when the ag- is solvated by two methanol molecules.
WOS标题词	science & technology ; physical sciences
类目[WOS]	physics, atomic, molecular & chemical
研究领域[WOS]	physics
关键词[WOS]	effective core potentials ; liquid methanol ; gas-phase ; ab-initio ; vibrational spectroscopy ; molecular calculations ; solvation dynamics ; electron-affinities ; dilute-solutions ; hcl solvation
收录类别	SCI
语种	英语
WOS记录号	WOS:000297139200009
公开日期	2015-11-17
内容类型	期刊论文
源URL	[http://159.226.238.44/handle/321008/142527]
专题	大连化学物理研究所_中国科学院大连化学物理研究所
作者单位	1.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Mol React Dynam, Dalian 116023, Peoples R China 2.Fudan Univ, Dept Chem, Shanghai Key Lab Mol Catalysts & Innovat Mat, Shanghai 200433, Peoples R China
推荐引用方式 GB/T 7714	Chi, Chao-xian,Xie, Hua,Cong, Ran,et al. Photoelectron Imaging of AgOCH3- and Ag-(CH3OH)(x) (x=1, 2)[J]. chinese journal of chemical physics,2011,24(5):557-562.
APA	Chi, Chao-xian,Xie, Hua,Cong, Ran,Tang, Zi-chao,&Zhou, Ming-fei.(2011).Photoelectron Imaging of AgOCH3- and Ag-(CH3OH)(x) (x=1, 2).chinese journal of chemical physics,24(5),557-562.
MLA	Chi, Chao-xian,et al."Photoelectron Imaging of AgOCH3- and Ag-(CH3OH)(x) (x=1, 2)".chinese journal of chemical physics 24.5(2011):557-562.