One-Pot Synthesis and Unpredicted Hydrogen Bonds of the Guanidinium Triflates from Readily Available Amines, Carbodiimides, and Zn(OTf)(2)

	One-Pot Synthesis and Unpredicted Hydrogen Bonds of the Guanidinium Triflates from Readily Available Amines, Carbodiimides, and Zn(OTf)(2)
	Li, Dongzhen 1; Wang, Yang 1; Zhang, Wen-Xiong 1,2; Zhang, Shaoguang 1; Guang, Jie 1; Xi, Zhenfeng 1
刊名	organometallics
	2011-10-10
卷号	30 期号:19 页码:5278-5283
英文摘要	the first synthesis of trisubstituted guanidinium triflates has been achieved by a simple one-step procedure from readily available amines, carbodiimides, and zn(otf)(2). x-ray analysis revealed they adopt 1-d chain-like or novel 3-d hydrogen-bonded networks, which have not been reported previously in the solid structure of guanidinium salts. isolation of a binuclear zinc complex and its subsequent carbodiimide insertion provide the insight into the mechanism for the formation of guanidinium triflates.
WOS标题词	science & technology ; physical sciences
类目[WOS]	chemistry, inorganic & nuclear ; chemistry, organic
研究领域[WOS]	chemistry
关键词[WOS]	earth-metal complexes ; efficient multicomponent reactions ; coordination chemistry ; catalytic addition ; ionic liquids ; substituted guanidines ; n-h ; structural-characterization ; organic-synthesis ; terminal alkynes
收录类别	SCI ; IC ; CCR
语种	英语
WOS记录号	WOS:000295347600025
公开日期	2015-11-17
内容类型	期刊论文
源URL	[http://159.226.238.44/handle/321008/142438]
专题	大连化学物理研究所_中国科学院大连化学物理研究所
作者单位	1.Peking Univ, BNLMS, Key Lab Bioorgan Chem & Mol Engn, Minist Educ,Coll Chem, Beijing 100871, Peoples R China 2.Nankai Univ, State Key Lab Elementoorgan Chem, Tianjin 300071, Peoples R China
推荐引用方式 GB/T 7714	Li, Dongzhen,Wang, Yang,Zhang, Wen-Xiong,et al. One-Pot Synthesis and Unpredicted Hydrogen Bonds of the Guanidinium Triflates from Readily Available Amines, Carbodiimides, and Zn(OTf)(2)[J]. organometallics,2011,30(19):5278-5283.
APA	Li, Dongzhen,Wang, Yang,Zhang, Wen-Xiong,Zhang, Shaoguang,Guang, Jie,&Xi, Zhenfeng.(2011).One-Pot Synthesis and Unpredicted Hydrogen Bonds of the Guanidinium Triflates from Readily Available Amines, Carbodiimides, and Zn(OTf)(2).organometallics,30(19),5278-5283.
MLA	Li, Dongzhen,et al."One-Pot Synthesis and Unpredicted Hydrogen Bonds of the Guanidinium Triflates from Readily Available Amines, Carbodiimides, and Zn(OTf)(2)".organometallics 30.19(2011):5278-5283.