Heat capacities and thermodynamic properties of one manganese-based MOFs

	Heat capacities and thermodynamic properties of one manganese-based MOFs
	Song, Li-Fang 3,4; Jiang, Chun-Hong 3,4; Jiao, Cheng-Li 3,4; Zhang, Jian 3; Sun, Li-Xian 3; Xu, Fen 5; Jiao, Qing-Zhu 5; Xing, Yong-Heng 5; Du, Yong 6; Cao, Zhong 7
刊名	journal of thermal analysis and calorimetry
	2010-12-01
卷号	102 期号:3 页码:1161-1166
关键词	Manganese Metal-organic framework Molar heat capacity TGA TMDSC
英文摘要	a metal-organic framework [mn(4,4'-bipy)(1,3-bdc)] (n) (mnmof, 1,3-bdc = 1,3-benzene dicarboxylate, 4,4'-bipy = 4,4'-bipyridine) has been synthesized hydrothermally and characterized by single crystal xrd and ft-ir spectrum. the low-temperature molar heat capacities of mnmof were measured by temperature-modulated differential scanning calorimetry for the first time. the thermodynamic parameters such as entropy and enthalpy relative to reference temperature 298.15 k were derived based on the above molar heat capacity data. moreover, the thermal stability and the decomposition mechanism of mnmof were investigated by thermogravimetry analysis-mass spectrometer. a two-stage mass loss was observed in air flow. ms curves indicated that the gas products of oxidative degradation were h2o, co2, no, and no2.
WOS标题词	science & technology ; physical sciences
类目[WOS]	chemistry, analytical ; chemistry, physical
研究领域[WOS]	chemistry
关键词[WOS]	differential scanning calorimetry ; metal-organic frameworks
收录类别	SCI
语种	英语
WOS记录号	WOS:000284433000045
公开日期	2015-11-17
内容类型	期刊论文
源URL	[http://159.226.238.44/handle/321008/141713]
专题	大连化学物理研究所_中国科学院大连化学物理研究所
作者单位	1.Dalian Inst Chem Phys, Chinese Acad Sci, Mat & Thermochemistry Lab, Dalian 116023, Peoples R China 2.Chinese Acad Sci, Grad Sch, Beijing 100049, Peoples R China 3.Chinese Acad Sci, Dalian Inst Chem Phys, Mat & Thermochem Lab, Dalian 116023, Peoples R China 4.Chinese Acad Sci, Grad Sch, Beijing 100049, Peoples R China 5.Liaoning Normal Univ, Fac Chem & Chem Engn, Dalian 116029, Peoples R China 6.Cent S Univ, State Key Lab Powder Met, Changsha 410083, Peoples R China 7.Changsha Univ Sci & Technol, Coll Chem & Biol Engn, Changsha 410076, Hunan, Peoples R China 8.Beijing Inst Technol, State Key Lab Explos Sci & Technol, Beijing 100081, Peoples R China
推荐引用方式 GB/T 7714	Song, Li-Fang,Jiang, Chun-Hong,Jiao, Cheng-Li,et al. Heat capacities and thermodynamic properties of one manganese-based MOFs[J]. journal of thermal analysis and calorimetry,2010,102(3):1161-1166.
APA	Song, Li-Fang.,Jiang, Chun-Hong.,Jiao, Cheng-Li.,Zhang, Jian.,Sun, Li-Xian.,...&Huang, Feng-Lei.(2010).Heat capacities and thermodynamic properties of one manganese-based MOFs.journal of thermal analysis and calorimetry,102(3),1161-1166.
MLA	Song, Li-Fang,et al."Heat capacities and thermodynamic properties of one manganese-based MOFs".journal of thermal analysis and calorimetry 102.3(2010):1161-1166.