Ambient temperature hydrogen desorption from LiAlH4-LiNH2 mediated by HMPA

	Ambient temperature hydrogen desorption from LiAlH4-LiNH2 mediated by HMPA
	Zheng, Xueli 1,2; Xu, Weiliang 3; Xiong, Zhitao 1; Chua, Yongshen 3; Wu, Guotao 1; Qin, Song 2; Chen, Hua 2; Chen, Ping 1
刊名	journal of materials chemistry
	2009
卷号	19 期号:44 页码:8426-8431
英文摘要	by adding a small amount of hmpa approximately 2.5 equivalent or ca. 8.1 wt% h-2 can be released from the lialh4-linh2 mixture at ambient temperature, which is similar to 370 degrees c lower than the corresponding solid-state dehydrogenation. nmr characterizations reveal the formation of intermediates, such as [alh] and [aln] species, during the dehydrogenation. linh2 induces the enrichment of [alh] species in the liquid phase which further reacts with linh2 to produce h-2, li2nh and al.
WOS标题词	science & technology ; physical sciences ; technology
类目[WOS]	chemistry, physical ; materials science, multidisciplinary
研究领域[WOS]	chemistry ; materials science
关键词[WOS]	n-h system ; thermal-decomposition ; complex hydrides ; chemical-reaction ; storage materials ; ammonia-borane ; metal-hydrides ; lithium ; lib0.33n0.67h2.67 ; dehydrogenation
收录类别	SCI
语种	英语
WOS记录号	WOS:000271744600022
公开日期	2015-11-17
内容类型	期刊论文
源URL	[http://159.226.238.44/handle/321008/141283]
专题	大连化学物理研究所_中国科学院大连化学物理研究所
作者单位	1.Dalian Inst Chem Phys, Dalian 116023, Peoples R China 2.Sichuan Univ, Key Lab Green Chem & Technol, Minist Educ, Inst Homogeneous Catalysis, Chengdu 610064, Peoples R China 3.Natl Univ Singapore, Dept Chem, Fac Sci, Singapore 117543, Singapore
推荐引用方式 GB/T 7714	Zheng, Xueli,Xu, Weiliang,Xiong, Zhitao,et al. Ambient temperature hydrogen desorption from LiAlH4-LiNH2 mediated by HMPA[J]. journal of materials chemistry,2009,19(44):8426-8431.
APA	Zheng, Xueli.,Xu, Weiliang.,Xiong, Zhitao.,Chua, Yongshen.,Wu, Guotao.,...&Chen, Ping.(2009).Ambient temperature hydrogen desorption from LiAlH4-LiNH2 mediated by HMPA.journal of materials chemistry,19(44),8426-8431.
MLA	Zheng, Xueli,et al."Ambient temperature hydrogen desorption from LiAlH4-LiNH2 mediated by HMPA".journal of materials chemistry 19.44(2009):8426-8431.