Thermodynamic properties of carbon dioxide expanded liquids and applications in chemical reactions

	Thermodynamic properties of carbon dioxide expanded liquids and applications in chemical reactions
	Yin Jianzhong 1; Ma Xiaorong 1; Zhang Xianzhen 1; Wang Aiqin 2
刊名	progress in chemistry
	2008-09-01
卷号	20 期号:9 页码:1251-1262
关键词	carbon dioxide expanded liquids solubility enhancement thermodynamic properties chemical reactions
英文摘要	carbon dioxide expanded liquids (cxls) have been considered as a kind of environmentally benign solvents. they often present some unique features such as high gas solubility, good mass transfer property, low viscosity, mild operation conditions, as well as less employment of organic solvents. so they are given more and more attentions by chemists and chemical engineering scientists. this paper reviews the recent studies on the volume expansibility, phase equilibrium thermodynamics, mass transfer properties, acidities, and conductivities of cxls, and summarizes the chemical reactions based on the cxls, including hydrogenation, hydroformylation and oxidation etc. finally, the existing problems associated with the cxls are analyzed and the research directions of cxls in future are also pointed out.
WOS标题词	science & technology ; physical sciences
类目[WOS]	chemistry, multidisciplinary
研究领域[WOS]	chemistry
关键词[WOS]	temperature ionic liquids ; fluid-phase equilibria ; co2-expanded liquids ; compressed co2 ; ternary-system ; enantioselective hydrogenation ; asymmetric hydrogenation ; selective hydrogenation ; heterogeneous catalysis ; supercritical fluids
收录类别	SCI
语种	英语
WOS记录号	WOS:000259465900002
公开日期	2015-11-17
内容类型	期刊论文
源URL	[http://159.226.238.44/handle/321008/141025]
专题	大连化学物理研究所_中国科学院大连化学物理研究所
作者单位	1.Dalian Univ Technol, Sch Chem Engn, Dalian 116012, Peoples R China 2.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Peoples R China
推荐引用方式 GB/T 7714	Yin Jianzhong,Ma Xiaorong,Zhang Xianzhen,et al. Thermodynamic properties of carbon dioxide expanded liquids and applications in chemical reactions[J]. progress in chemistry,2008,20(9):1251-1262.
APA	Yin Jianzhong,Ma Xiaorong,Zhang Xianzhen,&Wang Aiqin.(2008).Thermodynamic properties of carbon dioxide expanded liquids and applications in chemical reactions.progress in chemistry,20(9),1251-1262.
MLA	Yin Jianzhong,et al."Thermodynamic properties of carbon dioxide expanded liquids and applications in chemical reactions".progress in chemistry 20.9(2008):1251-1262.