The covalently bonded cellulose tris(3,5-dimethylphenylcarbamate) on a silica monolithic capillary column for enantioseparation in capillary electrochromatography

	The covalently bonded cellulose tris(3,5-dimethylphenylcarbamate) on a silica monolithic capillary column for enantioseparation in capillary electrochromatography
	Dong, Xiaoli 1,2; Wu, Ren'an 1; Dong, Jing 1; Wu, Minghuo 1; Zhu, Yan 2; Zou, Hanfa 1
刊名	journal of chromatography b-analytical technologies in the biomedical and life sciences
	2008-11-01
卷号	875 期号:1 页码:317-322
关键词	Capillary electrochromatography Cellulose tris(3 Covalently bonded chiral stationary phase Enantioseparation Silica monolithic column 5-dimethylphenylcarbamate)
英文摘要	a chiral capillary monolithic column for capillary electrochromatography (cec) was prepared by covalent bonding of cellulose tris(3,5-dimethylphenylcarbamate) (cdmpc) on the silica monolithic matrix within the confine of a 50-mu m i.d. bare fused silica capillary. several pairs of enantiomers including neutral and basic analytes were baseline resolved on the newly prepared chiral capillary monolithic column in cec with aqueous mobile phases. fast enantioseparation was achieved due to the favorable dynamic properties of silica monolith. the covalent bonding of cdmpc as the chiral stationary phase for cec also enabled the use of thf in mobile phase for enantioseparation of prazquantel by overcoming the incompatibility of thf and the physically coated cdmpc on a column. (c) 2008 published by elsevier b.v.
WOS标题词	science & technology ; life sciences & biomedicine ; physical sciences
类目[WOS]	biochemical research methods ; chemistry, analytical
研究领域[WOS]	biochemistry & molecular biology ; chemistry
关键词[WOS]	chiral stationary-phase ; liquid-chromatographic enantioseparations ; charged polyacrylamide-gels ; enantiomeric separations ; polysaccharide derivatives ; vancomycin ; tris(3,5-dichlorophenylcarbamate) ; size
收录类别	SCI
语种	英语
WOS记录号	WOS:000260945800042
公开日期	2015-11-17
内容类型	期刊论文
源URL	[http://159.226.238.44/handle/321008/140808]
专题	大连化学物理研究所_中国科学院大连化学物理研究所
作者单位	1.Chinese Acad Sci, Dalian Inst Chem Phys, Natl Chromatograph R&A Ctr, Dalian 116023, Peoples R China 2.Zhejiang Univ, Dept Chem, Hangzhou 310028, Peoples R China
推荐引用方式 GB/T 7714	Dong, Xiaoli,Wu, Ren'an,Dong, Jing,et al. The covalently bonded cellulose tris(3,5-dimethylphenylcarbamate) on a silica monolithic capillary column for enantioseparation in capillary electrochromatography[J]. journal of chromatography b-analytical technologies in the biomedical and life sciences,2008,875(1):317-322.
APA	Dong, Xiaoli,Wu, Ren'an,Dong, Jing,Wu, Minghuo,Zhu, Yan,&Zou, Hanfa.(2008).The covalently bonded cellulose tris(3,5-dimethylphenylcarbamate) on a silica monolithic capillary column for enantioseparation in capillary electrochromatography.journal of chromatography b-analytical technologies in the biomedical and life sciences,875(1),317-322.
MLA	Dong, Xiaoli,et al."The covalently bonded cellulose tris(3,5-dimethylphenylcarbamate) on a silica monolithic capillary column for enantioseparation in capillary electrochromatography".journal of chromatography b-analytical technologies in the biomedical and life sciences 875.1(2008):317-322.