Selective hydrogenation of cinnamaldehyde over carbon nanotube supported Pd-Ru catalyst
Qiu, Jieshan; Zhang, Hongzhe; Wang, Xiuna; Han, Hongmei; Liang, Changhai; Li, Can
刊名reaction kinetics and catalysis letters
2006-08-01
卷号88期号:2页码:269-275
关键词carbon nanotubes hydrogenation of cinnamaldehyde palladium and ruthenium
英文摘要carbon nanotube supported pd, ru and pd-ru catalysts have been prepared and tested with the hydrogenation of cinnamaldehyde as a probe reaction. it has been found that the cinnamaldehyde conversion and the selectivity towards the hydrogenation of c=o bond over pd-ru/pcnt catalyst could reach 56.6% and 79.1%, respectively, at 120 degrees c and 5.0 mpa, which is better than pd/pcnt and ru/pcnt catalysts under the same reaction conditions. it is assumed that the better performance of pd-ru/pcnt catalyst for cinnamaldehyde hydrogenation may be due to the synergic effect of pd and ru metals or the promoting effect of ru metal.
WOS标题词science & technology ; physical sciences
类目[WOS]chemistry, physical
研究领域[WOS]chemistry
关键词[WOS]alpha,beta-unsaturated aldehydes ; platinum
收录类别SCI
语种英语
WOS记录号WOS:000239050100009
公开日期2015-11-17
内容类型期刊论文
源URL[http://159.226.238.44/handle/321008/140156]  
专题大连化学物理研究所_中国科学院大连化学物理研究所
作者单位1.Dalian Univ Technol, Sch Chem Engn, Ctr Nanomat & Sci,Carbon Res Lab, State Key Lab Fine Chem, Dalian 116012, Peoples R China
2.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian, Peoples R China
3.Ruhr Univ Bochum, Lab Ind Chem, D-44780 Bochum, Germany
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GB/T 7714
Qiu, Jieshan,Zhang, Hongzhe,Wang, Xiuna,et al. Selective hydrogenation of cinnamaldehyde over carbon nanotube supported Pd-Ru catalyst[J]. reaction kinetics and catalysis letters,2006,88(2):269-275.
APA Qiu, Jieshan,Zhang, Hongzhe,Wang, Xiuna,Han, Hongmei,Liang, Changhai,&Li, Can.(2006).Selective hydrogenation of cinnamaldehyde over carbon nanotube supported Pd-Ru catalyst.reaction kinetics and catalysis letters,88(2),269-275.
MLA Qiu, Jieshan,et al."Selective hydrogenation of cinnamaldehyde over carbon nanotube supported Pd-Ru catalyst".reaction kinetics and catalysis letters 88.2(2006):269-275.
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