Partial oxidation of methane to syngas in BaCe0.15Fe0.85O3-delta membrane reactors

	Partial oxidation of methane to syngas in BaCe0.15Fe0.85O3-delta membrane reactors
	Zhu, Xuefeng ; Wang, HaiHui ; Cong, You ; Yang, Weishen
刊名	catalysis letters
	2006-11-01
卷号	111 期号:3-4 页码:179-185
关键词	oxygen permeation membrane reactor syngas stability perovskite oxides
英文摘要	dense planar ba0.15ce0.85feo3-delta(bcf1585) membrane reactors were investigated to produce syngas from methane. firstly, the membrane itself catalytic activity to methane was investigated using a blank bcf1585 without any catalysts. then a lilani vertical bar gamma-al2o3 catalyst was packed on the bcf1585 membrane surface to test the synergetic effects of the membrane and catalyst. it was found that the membrane itself has a poor catalytic activity to methane. the main products are co2 and c-2, and methane conversion is low due to the low oxygen permeation flux. however, after the catalyst was packed on the membrane surface, both methane conversion and oxygen permeation flux were greatly improved by the synergetic effect between the membrane and catalyst. carbon monoxide selectivity reached at 96% with methane conversion of up to 96%. the oxygen permeation flux reached at 3.0 ml/cm(2) stop min at 850 degrees c for a 1.5 mm disk membrane and can effectively be increased by reducing the thickness of the membranes. after operation for 140 h at 850 degrees c, the used membrane was examined with sem and edxs. the results revealed that the decomposition of the membrane materials could not be avoided under such conditions. oxygen partial pressure gradient across the membranes is suggested as a critical factor to accelerate the kinetic decomposition of the materials.
WOS标题词	science & technology ; physical sciences
类目[WOS]	chemistry, physical
研究领域[WOS]	chemistry
关键词[WOS]	oxygen-permeable membrane ; conducting ceramic membrane ; permeation ; separation ; conversion ; stability ; catalyst ; ethane
收录类别	SCI
语种	英语
WOS记录号	WOS:000241578200012
公开日期	2015-11-17
内容类型	期刊论文
源URL	[http://159.226.238.44/handle/321008/140153]
专题	大连化学物理研究所_中国科学院大连化学物理研究所
作者单位	1.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Peoples R China 2.Chinese Acad Sci, Grad Sch, Beijing, Peoples R China
推荐引用方式 GB/T 7714	Zhu, Xuefeng,Wang, HaiHui,Cong, You,et al. Partial oxidation of methane to syngas in BaCe0.15Fe0.85O3-delta membrane reactors[J]. catalysis letters,2006,111(3-4):179-185.
APA	Zhu, Xuefeng,Wang, HaiHui,Cong, You,&Yang, Weishen.(2006).Partial oxidation of methane to syngas in BaCe0.15Fe0.85O3-delta membrane reactors.catalysis letters,111(3-4),179-185.
MLA	Zhu, Xuefeng,et al."Partial oxidation of methane to syngas in BaCe0.15Fe0.85O3-delta membrane reactors".catalysis letters 111.3-4(2006):179-185.