Efficient catalytic asymmetric synthesis of alpha-substituted phenyloxyacetyloxy and aroyloxy phosphonates

	Efficient catalytic asymmetric synthesis of alpha-substituted phenyloxyacetyloxy and aroyloxy phosphonates
	Liu, Hui ; Zhou, Yong-Gui ; Yu, Zheng-Kun ; Xiao, Wen-Jing ; Liu, Sheng-Hua ; He, Hong-Wu
刊名	tetrahedron
	2006-11-27
卷号	62 期号:48 页码:11207-11217
关键词	asymmetric catalysis chirality phosphonate hydrogenation
英文摘要	optically active alpha-substituted phenyloxyacetyloxy and aroyloxy phosphonates have been synthesized via catalytic asymmetric hydrogenation of the corresponding prochiral alpha,beta-unsaturated phosphonates using rh(i)/(r,r)-me-duphos as the catalyst in methanol at 18 degrees c. the asymmetric hydrogenation reaction exhibits excellent enantioselectivity with enantiomeric excesses from 91 to 96%. (c) 2006 elsevier ltd. all rights reserved.
WOS标题词	science & technology ; physical sciences
类目[WOS]	chemistry, organic
研究领域[WOS]	chemistry
关键词[WOS]	highly enantioselective hydrogenation ; state analog inhibitors ; amino phosphonates ; hydroxy phosphonates ; acid-derivatives ; hiv-protease ; complexes ; phosphonopeptides ; enamides ; oxides
收录类别	SCI ; IC ; CCR
语种	英语
WOS记录号	WOS:000241967600021
公开日期	2015-11-17
内容类型	期刊论文
源URL	[http://159.226.238.44/handle/321008/140066]
专题	大连化学物理研究所_中国科学院大连化学物理研究所
作者单位	1.Cent China Normal Univ, Coll Chem, Minist Educ, Key Lab Pesticide & Chem Biol, Wuhan 430079, Hubei, Peoples R China 2.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Liaoning, Peoples R China
推荐引用方式 GB/T 7714	Liu, Hui,Zhou, Yong-Gui,Yu, Zheng-Kun,et al. Efficient catalytic asymmetric synthesis of alpha-substituted phenyloxyacetyloxy and aroyloxy phosphonates[J]. tetrahedron,2006,62(48):11207-11217.
APA	Liu, Hui,Zhou, Yong-Gui,Yu, Zheng-Kun,Xiao, Wen-Jing,Liu, Sheng-Hua,&He, Hong-Wu.(2006).Efficient catalytic asymmetric synthesis of alpha-substituted phenyloxyacetyloxy and aroyloxy phosphonates.tetrahedron,62(48),11207-11217.
MLA	Liu, Hui,et al."Efficient catalytic asymmetric synthesis of alpha-substituted phenyloxyacetyloxy and aroyloxy phosphonates".tetrahedron 62.48(2006):11207-11217.