Synthesis of novel ferrocenylphosphine-amidine ligands and their application in Pd-catalyzed asymmetric allylic alkylation

	Synthesis of novel ferrocenylphosphine-amidine ligands and their application in Pd-catalyzed asymmetric allylic alkylation
	Hu, XP; Chen, HL; Hu, XQ; Dai, HC; Bai, CM; Wang, JW; Zheng, Z
刊名	tetrahedron letters
	2002-12-09
卷号	43 期号:50 页码:9179-9182
英文摘要	a family of novel ferrocenylphosphine-amidine ligands derived from (r)-(s)-ppfnh2-r 5 was applied to the palladium-catalyzed asymmetric allylic alkylation of 1,3-diphenylprop-2-en-1-yl acetate 8a or pivalate 8b with dimethyl malonate. up to 94% e.e. was achieved when ligand 6b was used. (c) 2002 elsevier science ltd. all rights reserved.
WOS标题词	science & technology ; physical sciences
类目[WOS]	chemistry, organic
研究领域[WOS]	chemistry
关键词[WOS]	chiral ferrocenylphosphines ; aminophosphine ligands ; planar chirality ; p,n-ligands ; enantioselectivity ; hydrogenation ; substitution ; allylation
收录类别	SCI ; IC ; CCR
语种	英语
WOS记录号	WOS:000179353100041
公开日期	2015-11-10
内容类型	期刊论文
源URL	[http://159.226.238.44/handle/321008/139155]
专题	大连化学物理研究所_中国科学院大连化学物理研究所
作者单位	Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Peoples R China
推荐引用方式 GB/T 7714	Hu, XP,Chen, HL,Hu, XQ,et al. Synthesis of novel ferrocenylphosphine-amidine ligands and their application in Pd-catalyzed asymmetric allylic alkylation[J]. tetrahedron letters,2002,43(50):9179-9182.
APA	Hu, XP.,Chen, HL.,Hu, XQ.,Dai, HC.,Bai, CM.,...&Zheng, Z.(2002).Synthesis of novel ferrocenylphosphine-amidine ligands and their application in Pd-catalyzed asymmetric allylic alkylation.tetrahedron letters,43(50),9179-9182.
MLA	Hu, XP,et al."Synthesis of novel ferrocenylphosphine-amidine ligands and their application in Pd-catalyzed asymmetric allylic alkylation".tetrahedron letters 43.50(2002):9179-9182.