Experimental and theoretical investigations of the O(D-1) reaction with cyclopropane

	Experimental and theoretical investigations of the O(D-1) reaction with cyclopropane
	Wang, CC ; Shu, J ; Lin, JJ ; Lee, YT ; Yang, XM ; Nguyen, TL ; Mebel, AM
刊名	journal of chemical physics
	2002-05-15
卷号	116 期号:19 页码:8292-8299
英文摘要	in this report, the o(d-1)+c-c3h6 reaction has been investigated using the universal crossed molecular beam technique. angular resolved time-of-flight spectra have been measured for the observed reaction products in a single set of experiments. four reaction channels have been observed clearly for this reaction. in addition to the oh+c3h5 channel, the two microchannels for c2h4 formation and the h-atom formation channel are also present. different product angular distributions were measured for the observed product channels, indicating that each reaction channel occurs with distinctive dynamics. branching ratios for all observed reaction channels have also been estimated. high-level theoretical calculations have been performed on the energetics of this reaction, indicating two major insertion pathways are likely responsible for most of the reaction channels. (c) 2002 american institute of physics.
WOS标题词	science & technology ; physical sciences
类目[WOS]	physics, atomic, molecular & chemical
研究领域[WOS]	physics
关键词[WOS]	density-functional thermochemistry ; quadratic configuration-interaction ; potential-energy surface ; coupled-cluster singles ; vibrational distribution ; gaussian-2 ; o(1d2) ; ch3 ; hydrocarbons ; o((1)d)
收录类别	SCI
语种	英语
WOS记录号	WOS:000175297600007
公开日期	2015-11-10
内容类型	期刊论文
源URL	[http://159.226.238.44/handle/321008/139142]
专题	大连化学物理研究所_中国科学院大连化学物理研究所
作者单位	1.Acad Sinica, Inst Atom & Mol Sci, Hsinchu, Taiwan 2.Natl Tsing Hua Univ, Dept Chem, Hsinchu, Taiwan 3.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian, Peoples R China
推荐引用方式 GB/T 7714	Wang, CC,Shu, J,Lin, JJ,et al. Experimental and theoretical investigations of the O(D-1) reaction with cyclopropane[J]. journal of chemical physics,2002,116(19):8292-8299.
APA	Wang, CC.,Shu, J.,Lin, JJ.,Lee, YT.,Yang, XM.,...&Mebel, AM.(2002).Experimental and theoretical investigations of the O(D-1) reaction with cyclopropane.journal of chemical physics,116(19),8292-8299.
MLA	Wang, CC,et al."Experimental and theoretical investigations of the O(D-1) reaction with cyclopropane".journal of chemical physics 116.19(2002):8292-8299.