In situ FT-IR studies on the CO2 hydrogenation over the SiO2-supported RhM (M = Cr, Mo, W) complex catalysts

	In situ FT-IR studies on the CO2 hydrogenation over the SiO2-supported RhM (M = Cr, Mo, W) complex catalysts
	Shao, CP ; Chen, MS
刊名	journal of molecular catalysis a-chemical
	2001-02-15
卷号	166 期号:2 页码:331-335
关键词	CO2 hydrogenation in situ FT-IR bimetal complex catalyst
英文摘要	the in situ ft-ir spectra were used to study the co2 hydrogenation reactions over the sio2-supported heterobinuclear metal complex catalysts, rhm (m = cr, mo, w). the bands, which correspond to the formate species adsorbed on the catalysts, were observed. during the hydrogenation reactions, the adsorbed linear and bridged bridging co were not observed. the experimental results suggest that for the co2 and co hydrogenation reactions over the same catalysts, their catalytic active intermediate species and the reaction mechanisms should be different. (c) 2001 elsevier science b.v. all rights reserved.
WOS标题词	science & technology ; physical sciences
类目[WOS]	chemistry, physical
研究领域[WOS]	chemistry
关键词[WOS]	methanol synthesis
收录类别	SCI
语种	英语
WOS记录号	WOS:000167082900014
公开日期	2015-11-10
内容类型	期刊论文
源URL	[http://159.226.238.44/handle/321008/138871]
专题	大连化学物理研究所_中国科学院大连化学物理研究所
作者单位	1.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian, Peoples R China 2.Xiamen Univ, State Key Lab Phys Chem Solid Surface, Xiamen, Peoples R China
推荐引用方式 GB/T 7714	Shao, CP,Chen, MS. In situ FT-IR studies on the CO2 hydrogenation over the SiO2-supported RhM (M = Cr, Mo, W) complex catalysts[J]. journal of molecular catalysis a-chemical,2001,166(2):331-335.
APA	Shao, CP,&Chen, MS.(2001).In situ FT-IR studies on the CO2 hydrogenation over the SiO2-supported RhM (M = Cr, Mo, W) complex catalysts.journal of molecular catalysis a-chemical,166(2),331-335.
MLA	Shao, CP,et al."In situ FT-IR studies on the CO2 hydrogenation over the SiO2-supported RhM (M = Cr, Mo, W) complex catalysts".journal of molecular catalysis a-chemical 166.2(2001):331-335.