Femtosecond pump-probe photodissociation of OClO: direct observation of the (2)A(1) state and the role of accidental multiphoton resonance

	Femtosecond pump-probe photodissociation of OClO: direct observation of the (2)A(1) state and the role of accidental multiphoton resonance
	Sun, ZG ; Lou, NQ ; Nyman, G
刊名	chemical physics letters
	2004-07-21
卷号	393 期号:1-3 页码:204-208
英文摘要	previous pump-probe experiments on the ocio molecule are analyzed and a consistent interpretation of the experimental observations is proposed. we demonstrate that a direct observation of the very weak (2)a(1) state of ocio is possible with a proper femtosecond pulse, and suggest that it is necessary to introduce an accidental resonance of the probe pulse with the highly excited d or e states for understanding the observed distinct photodissociation dynamics of the (2)a(2) state using pump pulses of slightly different wavelengths. a transient abnormal peak, observed in the ocio+ ion signal after a stronger excitation, is also convincingly interpreted. (c) 2004 elsevier b.v. all rights reserved.
WOS标题词	science & technology ; physical sciences
类目[WOS]	chemistry, physical ; physics, atomic, molecular & chemical
研究领域[WOS]	chemistry ; physics
关键词[WOS]	wave-packet motion ; chlorine dioxide ; ionization path ; spectroscopy ; dynamics ; photoabsorption ; fragmentation ; perturbation ; phase ; pulse
收录类别	SCI
语种	英语
WOS记录号	WOS:000222887700037
公开日期	2015-11-10
内容类型	期刊论文
源URL	[http://159.226.238.44/handle/321008/138430]
专题	大连化学物理研究所_中国科学院大连化学物理研究所
作者单位	1.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Mol React Dynam, Dalian 116023, Peoples R China 2.Univ Gothenburg, Dept Chem, SE-41296 Gothenburg, Sweden
推荐引用方式 GB/T 7714	Sun, ZG,Lou, NQ,Nyman, G. Femtosecond pump-probe photodissociation of OClO: direct observation of the (2)A(1) state and the role of accidental multiphoton resonance[J]. chemical physics letters,2004,393(1-3):204-208.
APA	Sun, ZG,Lou, NQ,&Nyman, G.(2004).Femtosecond pump-probe photodissociation of OClO: direct observation of the (2)A(1) state and the role of accidental multiphoton resonance.chemical physics letters,393(1-3),204-208.
MLA	Sun, ZG,et al."Femtosecond pump-probe photodissociation of OClO: direct observation of the (2)A(1) state and the role of accidental multiphoton resonance".chemical physics letters 393.1-3(2004):204-208.