Rotational alignment of products from NOCl+Sr chemiluminescent reaction

	Rotational alignment of products from NOCl+Sr chemiluminescent reaction
	Zhan, JP; Yang, HP; Han, KL; Wang, ML; Deng, WQ; He, GZ; Lou, NQ
刊名	journal of chemical physics
	1998-08-01
卷号	109 期号:5 页码:1819-1823
英文摘要	the chemiluminescent reactions sr + nocl-->srcl(a,b) + no are studied under the single collision conditions in a beam-gas arrangement. the product rotational alignment [p-2( (j) over cap'.(k) over cap)] = -0.40 +/-0.05 for srcl(b) is obtained from sr+nocl chemiluminescent reactions. in addition, the electronic state branching ratio and the product vibrational state distribution have been roughly estimated by simulating the chemiluminescent spectra of srcl. quasiclassical trajectory (qct) calculations for the sr+nocl reaction as a three-body system have been carried out. the calculated results agree;well with the experimental ones. (c) 1998 american institute of physics.
WOS标题词	science & technology ; physical sciences
类目[WOS]	physics, atomic, molecular & chemical
研究领域[WOS]	physics
关键词[WOS]	laser-induced fluorescence ; spin-orbit state ; angular-momentum ; halogenated methanes ; exchange-reactions ; reaction dynamics ; alkyl bromides ; polarization ; dependence ; velocity
收录类别	SCI
语种	英语
WOS记录号	WOS:000075066300030
公开日期	2015-11-10
内容类型	期刊论文
源URL	[http://159.226.238.44/handle/321008/138180]
专题	大连化学物理研究所_中国科学院大连化学物理研究所
作者单位	Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Mol React Dynam, Dalian 116023, Peoples R China
推荐引用方式 GB/T 7714	Zhan, JP,Yang, HP,Han, KL,et al. Rotational alignment of products from NOCl+Sr chemiluminescent reaction[J]. journal of chemical physics,1998,109(5):1819-1823.
APA	Zhan, JP.,Yang, HP.,Han, KL.,Wang, ML.,Deng, WQ.,...&Lou, NQ.(1998).Rotational alignment of products from NOCl+Sr chemiluminescent reaction.journal of chemical physics,109(5),1819-1823.
MLA	Zhan, JP,et al."Rotational alignment of products from NOCl+Sr chemiluminescent reaction".journal of chemical physics 109.5(1998):1819-1823.