Cation spectroscopy of o-fluoroanisole and p-fluoroanisole by two-color resonant two-photon mass-analyzed threshold ionization
Shiung, Kui Shiu1,2; Yu, Dan1,3; Tzeng, Sheng Yuan1,2; Tzeng, Wen Bih1,2
刊名chemical physics letters
2012-02-06
卷号524页码:38-41
英文摘要we applied the two-color resonant two-photon mass-analyzed threshold ionization spectroscopic technique to record the cation spectra of o-fluoroanisole and p-fluoroanisole. the adiabatic ionization energies of these two structural isomers were found to be 67354 +/- 5 and 66437 +/- 5 cm(-1), respectively. the observed active normal modes of the cations mainly result from the in-plane ring and substituent-sensitive vibrations. the results suggest that the relative location of the f and och3 substituents can slightly influence the transition energy and molecular vibrations. (c) 2012 elsevier b. v. all rights reserved.
WOS标题词science & technology ; physical sciences
类目[WOS]chemistry, physical ; physics, atomic, molecular & chemical
研究领域[WOS]chemistry ; physics
关键词[WOS]singlet pi>>-pi states ; ab-initio calculations ; infrared-spectroscopy ; dipole moments ; gas-phase ; fluorophenol ; 2-fluoroanisole ; rotamers ; 4-fluoroanisole ; methoxyphenol
收录类别SCI
语种英语
WOS记录号WOS:000299317600007
公开日期2015-11-10
内容类型期刊论文
源URL[http://159.226.238.44/handle/321008/138044]  
专题大连化学物理研究所_中国科学院大连化学物理研究所
作者单位1.Acad Sinica, Inst Atom & Mol Sci, Taipei 10617, Taiwan
2.Natl Taiwan Normal Univ, Dept Chem, Taipei 11677, Taiwan
3.Chinese Acad Sci, State Key Lab Mol React Dynam, Inst Chem, Beijing 100190, Peoples R China
推荐引用方式
GB/T 7714
Shiung, Kui Shiu,Yu, Dan,Tzeng, Sheng Yuan,et al. Cation spectroscopy of o-fluoroanisole and p-fluoroanisole by two-color resonant two-photon mass-analyzed threshold ionization[J]. chemical physics letters,2012,524:38-41.
APA Shiung, Kui Shiu,Yu, Dan,Tzeng, Sheng Yuan,&Tzeng, Wen Bih.(2012).Cation spectroscopy of o-fluoroanisole and p-fluoroanisole by two-color resonant two-photon mass-analyzed threshold ionization.chemical physics letters,524,38-41.
MLA Shiung, Kui Shiu,et al."Cation spectroscopy of o-fluoroanisole and p-fluoroanisole by two-color resonant two-photon mass-analyzed threshold ionization".chemical physics letters 524(2012):38-41.
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