Cation spectroscopy of o-fluoroanisole and p-fluoroanisole by two-color resonant two-photon mass-analyzed threshold ionization | |
Shiung, Kui Shiu1,2; Yu, Dan1,3; Tzeng, Sheng Yuan1,2; Tzeng, Wen Bih1,2 | |
刊名 | chemical physics letters
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2012-02-06 | |
卷号 | 524页码:38-41 |
英文摘要 | we applied the two-color resonant two-photon mass-analyzed threshold ionization spectroscopic technique to record the cation spectra of o-fluoroanisole and p-fluoroanisole. the adiabatic ionization energies of these two structural isomers were found to be 67354 +/- 5 and 66437 +/- 5 cm(-1), respectively. the observed active normal modes of the cations mainly result from the in-plane ring and substituent-sensitive vibrations. the results suggest that the relative location of the f and och3 substituents can slightly influence the transition energy and molecular vibrations. (c) 2012 elsevier b. v. all rights reserved. |
WOS标题词 | science & technology ; physical sciences |
类目[WOS] | chemistry, physical ; physics, atomic, molecular & chemical |
研究领域[WOS] | chemistry ; physics |
关键词[WOS] | singlet pi>>-pi states ; ab-initio calculations ; infrared-spectroscopy ; dipole moments ; gas-phase ; fluorophenol ; 2-fluoroanisole ; rotamers ; 4-fluoroanisole ; methoxyphenol |
收录类别 | SCI |
语种 | 英语 |
WOS记录号 | WOS:000299317600007 |
公开日期 | 2015-11-10 |
内容类型 | 期刊论文 |
源URL | [http://159.226.238.44/handle/321008/138044] ![]() |
专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
作者单位 | 1.Acad Sinica, Inst Atom & Mol Sci, Taipei 10617, Taiwan 2.Natl Taiwan Normal Univ, Dept Chem, Taipei 11677, Taiwan 3.Chinese Acad Sci, State Key Lab Mol React Dynam, Inst Chem, Beijing 100190, Peoples R China |
推荐引用方式 GB/T 7714 | Shiung, Kui Shiu,Yu, Dan,Tzeng, Sheng Yuan,et al. Cation spectroscopy of o-fluoroanisole and p-fluoroanisole by two-color resonant two-photon mass-analyzed threshold ionization[J]. chemical physics letters,2012,524:38-41. |
APA | Shiung, Kui Shiu,Yu, Dan,Tzeng, Sheng Yuan,&Tzeng, Wen Bih.(2012).Cation spectroscopy of o-fluoroanisole and p-fluoroanisole by two-color resonant two-photon mass-analyzed threshold ionization.chemical physics letters,524,38-41. |
MLA | Shiung, Kui Shiu,et al."Cation spectroscopy of o-fluoroanisole and p-fluoroanisole by two-color resonant two-photon mass-analyzed threshold ionization".chemical physics letters 524(2012):38-41. |
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