Sulfonic Acid Resin-Catalyzed Oxidation of Aldehydes to Carboxylic Acids by Hydrogen Peroxide

	Sulfonic Acid Resin-Catalyzed Oxidation of Aldehydes to Carboxylic Acids by Hydrogen Peroxide
	Yang, Xiaomei 1; Tang, Si 1; Lu, Tianliang 1; Chen, Chen 2; Zhou, Lipeng 1; Su, Yunlai 1; Xu, Jie 2
刊名	synthetic communications
	2013-03-01
卷号	43 期号:7 页码:979-985
关键词	Aldehydes carboxylic acids hydrogen peroxide oxidation sulfonic acid resin
英文摘要	oxidation of benzaldehyde to benzoic acid can be performed efficiently with 30% h2o2 as the oxidant and sulfonic acid resin amberlyst 15 as the catalyst. the reactivities of benzaldehyde derivatives are determined by both hindrance effect and electron effect of substituents, and benzaldehyde derivatives with electron-withdrawing group at the meta- or para-position are highly active and almost quantitatively converted into their corresponding acids. in addition, this method also works well for the oxidation of aliphatic aldehydes. the key characteristic of the procedure is that the catalyst is recyclable.
WOS标题词	science & technology ; physical sciences
类目[WOS]	chemistry, organic
研究领域[WOS]	chemistry
关键词[WOS]	aromatic-aldehydes ; selective oxidation ; organic-solvent
收录类别	SCI ; CCR
语种	英语
WOS记录号	WOS:000313418700006
公开日期	2015-11-10
内容类型	期刊论文
源URL	[http://159.226.238.44/handle/321008/137980]
专题	大连化学物理研究所_中国科学院大连化学物理研究所
作者单位	1.Zhengzhou Univ, Dept Chem, Zhengzhou 450001, Peoples R China 2.Chinese Acad Sci, State Key Lab Catalysis, Dalian Inst Chem Phys, Dalian 116023, Peoples R China
推荐引用方式 GB/T 7714	Yang, Xiaomei,Tang, Si,Lu, Tianliang,et al. Sulfonic Acid Resin-Catalyzed Oxidation of Aldehydes to Carboxylic Acids by Hydrogen Peroxide[J]. synthetic communications,2013,43(7):979-985.
APA	Yang, Xiaomei.,Tang, Si.,Lu, Tianliang.,Chen, Chen.,Zhou, Lipeng.,...&Xu, Jie.(2013).Sulfonic Acid Resin-Catalyzed Oxidation of Aldehydes to Carboxylic Acids by Hydrogen Peroxide.synthetic communications,43(7),979-985.
MLA	Yang, Xiaomei,et al."Sulfonic Acid Resin-Catalyzed Oxidation of Aldehydes to Carboxylic Acids by Hydrogen Peroxide".synthetic communications 43.7(2013):979-985.