BODIPY-based fluorometric sensor array for the highly sensitive identification of heavy-metal ions | |
Niu, Li-Ya1; Li, Hui2; Feng, Liang2; Guan, Ying-Shi1; Chen, Yu-Zhe1; Duan, Chun-Feng2; Wu, Li-Zhu1; Guan, Ya-Feng2; Tung, Chen-Ho1; Yang, Qing-Zheng1 | |
刊名 | analytica chimica acta
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2013-05-02 | |
卷号 | 775页码:93-99 |
关键词 | 4 Multipyridyl ligand Fluorescent indicator Sensor array Heavy-metal ions 4-Difluoro-4-bora-3a 4a-diaza-s-indacene |
英文摘要 | a bodipy(4,4-difluoro-4-bora-3a,4a-diaza-s-indacene)-based fluorometric sensor array has been developed for the highly sensitive detection of eight heavy-metal ions at micromolar concentration. the di-2-picolyamine (dpa) derivatives combine high affinities for a variety of heavy-metal ions with the capacity to perturb the fluorescence properties of bodipy, making them perfectly suitable for the design of fluorometric sensor arrays for heavy-metal ions. 12 cross-reactive bodipy fluorescent indicators provide facile identification of the heavy-metal ions using a standard chemometric approach (hierarchical clustering analysis); no misclassifications were found over 45 trials. clear differentiation among heavy-metal ions as a function of concentration was also achieved, even down to 10(-7) m. a semi-quantitative interpolation of the heavy-metal concentration is obtained by comparing the total euclidean distance of the measurement with a set of known concentrations in the library. (c) 2013 elsevier b.v. all rights reserved. |
WOS标题词 | science & technology ; physical sciences |
类目[WOS] | chemistry, analytical |
研究领域[WOS] | chemistry |
关键词[WOS] | ratiometric fluorescent sensor ; intramolecular charge-transfer ; zinc ions ; energy-transfer ; living cells ; turn-on ; dyes ; functionalization ; recognition ; chemosensor |
收录类别 | SCI |
语种 | 英语 |
WOS记录号 | WOS:000318388900010 |
公开日期 | 2015-11-10 |
内容类型 | 期刊论文 |
源URL | [http://159.226.238.44/handle/321008/137587] ![]() |
专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
作者单位 | 1.Chinese Acad Sci, Tech Inst Phys & Chem, Key Lab Photochem Convers & Optoelect Mat, Beijing 100190, Peoples R China 2.Chinese Acad Sci, Dalian Inst Chem Phys, Key Lab Separat Sci Analyt Chem CAS, Lab Instrumentat & Analyt Chem, Dalian 116023, Liaoning, Peoples R China |
推荐引用方式 GB/T 7714 | Niu, Li-Ya,Li, Hui,Feng, Liang,et al. BODIPY-based fluorometric sensor array for the highly sensitive identification of heavy-metal ions[J]. analytica chimica acta,2013,775:93-99. |
APA | Niu, Li-Ya.,Li, Hui.,Feng, Liang.,Guan, Ying-Shi.,Chen, Yu-Zhe.,...&Yang, Qing-Zheng.(2013).BODIPY-based fluorometric sensor array for the highly sensitive identification of heavy-metal ions.analytica chimica acta,775,93-99. |
MLA | Niu, Li-Ya,et al."BODIPY-based fluorometric sensor array for the highly sensitive identification of heavy-metal ions".analytica chimica acta 775(2013):93-99. |
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