BODIPY-based fluorometric sensor array for the highly sensitive identification of heavy-metal ions
Niu, Li-Ya1; Li, Hui2; Feng, Liang2; Guan, Ying-Shi1; Chen, Yu-Zhe1; Duan, Chun-Feng2; Wu, Li-Zhu1; Guan, Ya-Feng2; Tung, Chen-Ho1; Yang, Qing-Zheng1
刊名analytica chimica acta
2013-05-02
卷号775页码:93-99
关键词4 Multipyridyl ligand Fluorescent indicator Sensor array Heavy-metal ions 4-Difluoro-4-bora-3a 4a-diaza-s-indacene
英文摘要a bodipy(4,4-difluoro-4-bora-3a,4a-diaza-s-indacene)-based fluorometric sensor array has been developed for the highly sensitive detection of eight heavy-metal ions at micromolar concentration. the di-2-picolyamine (dpa) derivatives combine high affinities for a variety of heavy-metal ions with the capacity to perturb the fluorescence properties of bodipy, making them perfectly suitable for the design of fluorometric sensor arrays for heavy-metal ions. 12 cross-reactive bodipy fluorescent indicators provide facile identification of the heavy-metal ions using a standard chemometric approach (hierarchical clustering analysis); no misclassifications were found over 45 trials. clear differentiation among heavy-metal ions as a function of concentration was also achieved, even down to 10(-7) m. a semi-quantitative interpolation of the heavy-metal concentration is obtained by comparing the total euclidean distance of the measurement with a set of known concentrations in the library. (c) 2013 elsevier b.v. all rights reserved.
WOS标题词science & technology ; physical sciences
类目[WOS]chemistry, analytical
研究领域[WOS]chemistry
关键词[WOS]ratiometric fluorescent sensor ; intramolecular charge-transfer ; zinc ions ; energy-transfer ; living cells ; turn-on ; dyes ; functionalization ; recognition ; chemosensor
收录类别SCI
语种英语
WOS记录号WOS:000318388900010
公开日期2015-11-10
内容类型期刊论文
源URL[http://159.226.238.44/handle/321008/137587]  
专题大连化学物理研究所_中国科学院大连化学物理研究所
作者单位1.Chinese Acad Sci, Tech Inst Phys & Chem, Key Lab Photochem Convers & Optoelect Mat, Beijing 100190, Peoples R China
2.Chinese Acad Sci, Dalian Inst Chem Phys, Key Lab Separat Sci Analyt Chem CAS, Lab Instrumentat & Analyt Chem, Dalian 116023, Liaoning, Peoples R China
推荐引用方式
GB/T 7714
Niu, Li-Ya,Li, Hui,Feng, Liang,et al. BODIPY-based fluorometric sensor array for the highly sensitive identification of heavy-metal ions[J]. analytica chimica acta,2013,775:93-99.
APA Niu, Li-Ya.,Li, Hui.,Feng, Liang.,Guan, Ying-Shi.,Chen, Yu-Zhe.,...&Yang, Qing-Zheng.(2013).BODIPY-based fluorometric sensor array for the highly sensitive identification of heavy-metal ions.analytica chimica acta,775,93-99.
MLA Niu, Li-Ya,et al."BODIPY-based fluorometric sensor array for the highly sensitive identification of heavy-metal ions".analytica chimica acta 775(2013):93-99.
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