Formation of Halogen Bond-Based 2D Supramolecular Assemblies by Electric Manipulation

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	Formation of Halogen Bond-Based 2D Supramolecular Assemblies by Electric Manipulation
	Zheng, Qing-Na 1,2,3; Liu, Xuan-He 1,2,3; Chen, Ting 1,2; Yan, Hui-Juan 1,2; Cook, Timothy 4,5; Wang, Dong 1,2; Stang, Peter J.4; Wan, Li-Jun 1,2
刊名	JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
	2015-05-20
卷号	137 期号:19 页码:6128-6131
英文摘要	Halogen bonding has attracted much attention recently as an important driving force for supramolecular assembly and crystal engineering. Herein, we demonstrate for the first time the formation of a halogen bond-based open porous network on a graphite surface using ethynylpyridine and aryl-halide based building blocks. We found that the electrical stimuli of a scanning tunneling microscopy (STM) tip can induce the formation of a binary supramolecular structure on the basis of halogen bond formation between terminal pyridyl groups and perfluoro-iodobenzene. This electrical manipulation method can be applied to engineer a series of linear or porous structures by selecting halogen bond donor and acceptor fragments with different symmetries, as the directional interactions ultimately determine the structural outcome.
收录类别	SCI
语种	英语
公开日期	2015-11-02
内容类型	期刊论文
源URL	[http://ir.iccas.ac.cn/handle/121111/28137]
专题	化学研究所_分子纳米结构与纳米技术实验室
作者单位	1.Chinese Acad Sci, Key Lab Mol Nanostruct & Nanotechnol, Inst Chem, Beijing 100190, Peoples R China 2.Chinese Acad Sci, Beijing Natl Lab Mol Sci, Inst Chem, Beijing 100190, Peoples R China 3.Chinese Acad Sci, Grad Univ, Beijing 100049, Peoples R China 4.Univ Utah, Dept Chem, Salt Lake City, UT 84112 USA 5.SUNY Buffalo, Dept Chem, Buffalo, NY 14260 USA
推荐引用方式 GB/T 7714	Zheng, Qing-Na,Liu, Xuan-He,Chen, Ting,et al. Formation of Halogen Bond-Based 2D Supramolecular Assemblies by Electric Manipulation[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY,2015,137(19):6128-6131.
APA	Zheng, Qing-Na.,Liu, Xuan-He.,Chen, Ting.,Yan, Hui-Juan.,Cook, Timothy.,...&Wan, Li-Jun.(2015).Formation of Halogen Bond-Based 2D Supramolecular Assemblies by Electric Manipulation.JOURNAL OF THE AMERICAN CHEMICAL SOCIETY,137(19),6128-6131.
MLA	Zheng, Qing-Na,et al."Formation of Halogen Bond-Based 2D Supramolecular Assemblies by Electric Manipulation".JOURNAL OF THE AMERICAN CHEMICAL SOCIETY 137.19(2015):6128-6131.