Novel functional hybrid silica sol-gel coating for copper protection via in situ thiol-ene click reaction
Peng, Shusen ; Zeng, Zhixiang ; Zhao, Wenjie ; Li, He ; Chen, Jianmin ; Han, Jin ; Wu, Xuedong
刊名RSC ADVANCES
2014
卷号4期号:30页码:15776
中文摘要A novel anticorrosion coating, which crosslinks with inorganic bonds (Si-O-Si) and organic bonds (C- S-C), is prepared on copper through an in situ sol-gel method and thiol- ene click reaction. The hybrid sol solution containing mercapto and vinyl groups (MVFS) is prepared from hydrolysis and condensation of vinyltriethoxysilane (VTES), tetraethoxysilane (TEOS) and 3- mercaptopropyltrimethoxysilane (MPMS). The thiol- ene click reaction was initiated with a thermal initiator after the sol solution was applied on the copper surface. Various corresponding methods are carried out to investigate this novel coating's properties. Experimental results demonstrate that the formation of organic crosslinking bonds deriving from thiol-ene click reaction can enhance the protection performance of the MVFS material for copper.
公开日期2015-09-20
内容类型期刊论文
源URL[http://ir.nimte.ac.cn/handle/174433/12030]  
专题宁波材料技术与工程研究所_2014专题
推荐引用方式
GB/T 7714
Peng, Shusen,Zeng, Zhixiang,Zhao, Wenjie,et al. Novel functional hybrid silica sol-gel coating for copper protection via in situ thiol-ene click reaction[J]. RSC ADVANCES,2014,4(30):15776.
APA Peng, Shusen.,Zeng, Zhixiang.,Zhao, Wenjie.,Li, He.,Chen, Jianmin.,...&Wu, Xuedong.(2014).Novel functional hybrid silica sol-gel coating for copper protection via in situ thiol-ene click reaction.RSC ADVANCES,4(30),15776.
MLA Peng, Shusen,et al."Novel functional hybrid silica sol-gel coating for copper protection via in situ thiol-ene click reaction".RSC ADVANCES 4.30(2014):15776.
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