An ionic liquid extraction process for the separation of indole from wash oil
Jiao, Tiantian1; Zhuang, Xulei1; He, Hongyan1; Zhao, Lihong2; Li, Chunshan1; Chen, Hongnan1; Zhang, Suojiang1
刊名GREEN CHEMISTRY
2015
卷号17期号:7页码:3783-3790
ISSN号1463-9262
英文摘要Indole is an important industrial substance derived from wash oil, and the traditional alkali fusion method causes serious environmental problems. In this research, imidazolium-based ionic liquids (IBILs) were developed as new extraction agents to separate indole from wash oil with extraction efficiencies of more than 90%. The influence of the IBIL structure was explored. The extraction efficiency and the distribution coefficient of indole were used as the indexes to evaluate the IBIL extraction ability. The key experimental parameters, such as the initial indole concentration, extraction time, extraction temperature, and volume ratio of IBIL-to-model wash oil, were investigated to obtain the optimum conditions. The separation mechanism was studied by analyzing the chemical bonds using spectrographic analysis and molecular simulations. The IBILs were recycled by back-extraction and they exhibited good recycling properties with no obvious reduction and a high extraction efficiency. Finally, the optimal process was conducted based on the process simulation.
WOS标题词Science & Technology ; Physical Sciences
类目[WOS]Chemistry, Multidisciplinary
研究领域[WOS]Chemistry
关键词[WOS]SOLVENT-EXTRACTION ; AMINO-ACIDS ; COAL-TAR ; BENZENE ; PHENOLS
收录类别SCI
语种英语
WOS记录号WOS:000357620900017
内容类型期刊论文
源URL[http://ir.ipe.ac.cn/handle/122111/19388]  
专题过程工程研究所_多相复杂系统国家重点实验室
作者单位1.Chinese Acad Sci, Beijing Key Lab Ion Liquids Clean Proc, State Key Lab Multiphase Complex Syst, Key Lab Green Proc & Engn,Inst Proc Engn, Beijing 100190, Peoples R China
2.Henan Energy Chem Ind Grp Co Ltd, Zhengzhou 450000, Peoples R China
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GB/T 7714
Jiao, Tiantian,Zhuang, Xulei,He, Hongyan,et al. An ionic liquid extraction process for the separation of indole from wash oil[J]. GREEN CHEMISTRY,2015,17(7):3783-3790.
APA Jiao, Tiantian.,Zhuang, Xulei.,He, Hongyan.,Zhao, Lihong.,Li, Chunshan.,...&Zhang, Suojiang.(2015).An ionic liquid extraction process for the separation of indole from wash oil.GREEN CHEMISTRY,17(7),3783-3790.
MLA Jiao, Tiantian,et al."An ionic liquid extraction process for the separation of indole from wash oil".GREEN CHEMISTRY 17.7(2015):3783-3790.
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