Progress in development and application of solid-state NMR for solid acid catalysis

CORC > 武汉物理与数学研究所 > 中国科学院武汉物理与数学研究所 > 磁共振应用研究部

	Progress in development and application of solid-state NMR for solid acid catalysis
	Zheng Anmin 1; Huang Shing-Jong 2; Wang Qiang 1; Zhang Hailu 3; Deng Feng 1; Liu Shang-Bin 4,5
刊名	CHINESE JOURNAL OF CATALYSIS
	2013-03-01
卷号	34 期号:3 页码:436-491
关键词	Solid-state NMR spectroscopy Solid acid catalyst Probe molecule Acidity Catalytic reaction mechanism
英文摘要	Solid acid catalysts have been widely used in petrochemical industry and their catalytic activities are normally dictated by their acidities. Unlike conventional acidity characterization techniques such as titration, infrared, or temperature-programmed desorption, detailed acid features of solid acids, such as type, distribution, concentration, and strength of acid sites may be attained by advanced methods involving pertinent probe molecules and state-of-the-art solid-state nuclear magnetic resonance (SSNMR) techniques, i.e. double resonance and two-dimensional correlation spectroscopies. In addition, in situ solid-state NMR method is capable of probing the guest/host properties of the reactant at the active centers of the catalysts as well as the intermediate species formed during conversion. It provides direct experimental evidence for exploring the mechanism of catalytic reaction. In this report, the fundamental theory and the recent developments in solid-state NMR are reviewed with specific focus on relevant applications in structure and acidity characterization of solid acid catalysts and catalytic mechanisms. (C) 2013, Dalian Institute of Chemical Physics, Chinese Academy of Sciences. Published by Elsevier B.V. All rights reserved.
WOS标题词	Science & Technology ; Physical Sciences ; Technology
类目[WOS]	Chemistry, Applied ; Chemistry, Physical ; Engineering, Chemical
研究领域[WOS]	Chemistry ; Engineering
关键词[WOS]	NUCLEAR-MAGNETIC-RESONANCE ; ANGLE-SPINNING NMR ; IN-SITU NMR ; PROBE MOLECULE TRIMETHYLPHOSPHINE ; INTEGER QUADRUPOLAR NUCLEI ; C-13 CHEMICAL-SHIFT ; H-1/AL-27 TRAPDOR NMR ; MULTIPLE-PULSE NMR ; MAGIC-ANGLE ; ZEOLITE HY
收录类别	SCI
语种	英语
WOS记录号	WOS:000317873600003
公开日期	2015-07-14
内容类型	期刊论文
源URL	[http://ir.wipm.ac.cn/handle/112942/1032]
专题	武汉物理与数学研究所_磁共振应用研究部
作者单位	1.Chinese Acad Sci, Wuhan Inst Phys & Math, Wuhan Ctr Magnet Resonance, State Key Lab Magnet Resonance & Atom & Mol Phys, Wuhan 430071, Hubei, Peoples R China 2.Natl Taiwan Univ, Dept Chem, Taipei 10617, Taiwan 3.Chinese Acad Sci, Suzhou Inst Nanotech & Nanobion, Suzhou 215123, Jiangsu, Peoples R China 4.Acad Sinica, Inst Atom & Mol Sci, Taipei 10617, Taiwan 5.Natl Taiwan Normal Univ, Dept Chem, Taipei 11677, Taiwan
推荐引用方式 GB/T 7714	Zheng Anmin,Huang Shing-Jong,Wang Qiang,et al. Progress in development and application of solid-state NMR for solid acid catalysis[J]. CHINESE JOURNAL OF CATALYSIS,2013,34(3):436-491.
APA	Zheng Anmin,Huang Shing-Jong,Wang Qiang,Zhang Hailu,Deng Feng,&Liu Shang-Bin.(2013).Progress in development and application of solid-state NMR for solid acid catalysis.CHINESE JOURNAL OF CATALYSIS,34(3),436-491.
MLA	Zheng Anmin,et al."Progress in development and application of solid-state NMR for solid acid catalysis".CHINESE JOURNAL OF CATALYSIS 34.3(2013):436-491.