Time-resolved photoelectron spectroscopy of bulk liquids at ultra-low kinetic energy | |
Tang, Ying1,2; Suzuki, Yoshi-ichi1,2; Shen, Huan1,4; Sekiguchi, Kentaro1,2; Kurahashi, Naoya1; Nishizawa, Kiyoshi3; Zuo, Peng3; Suzuki, Toshinori1,2,3 | |
刊名 | CHEMICAL PHYSICS LETTERS
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2010-07-09 | |
卷号 | 494期号:1-3页码:111-116 |
产权排序 | 第四 |
英文摘要 | Time-resolved photoelectron spectroscopy (TR-PES) of ultrafast dynamics in solution is presented. To measure the photoelectron kinetic energy distribution (PKED) that is free from inelastic scattering in solution, photoelectrons were generated with ultra-low kinetic energies (ULKE: <5 eV). Time constants of the elementary processes in the charge-transfer-to-solvent (CTTS) reaction from I to bulk water were in excellent agreement with those obtained by transient absorption spectroscopy, demonstrating the bulk-sensitivity of TR-PES-ULKE. The analysis suggests that the CTTS reaction proceeds via two intermediates, and that 30% of the first intermediate and 70% of the second intermediate respectively are quenched by geminate recombination between the electron and the neutral iodine atom. (C) 2010 Elsevier B.V. All rights reserved. |
学科主题 | 原子分子物理学 |
WOS标题词 | Science & Technology ; Physical Sciences |
类目[WOS] | Chemistry, Physical ; Physics, Atomic, Molecular & Chemical |
研究领域[WOS] | Chemistry ; Physics |
关键词[WOS] | MEAN FREE PATHS ; SOLVATED ELECTRONS ; DYNAMICS ; PHOTODETACHMENT ; SOLVENT ; WATER ; RANGE |
收录类别 | SCI |
语种 | 英语 |
WOS记录号 | WOS:000279368000022 |
内容类型 | 期刊论文 |
源URL | [http://ir.wipm.ac.cn/handle/112942/2056] ![]() |
专题 | 武汉物理与数学研究所_2011年以前论文发表(包括2011年) |
作者单位 | 1.Kyoto Univ, Dept Chem, Grad Sch Sci, Kyoto 6068502, Japan 2.Japan Sci & Technol Agcy, CREST, Chiyoda Ku, Tokyo 1020075, Japan 3.RIKEN, Adv Sci Inst, Chem Dynam Lab, Wako, Saitama 3510198, Japan 4.Chinese Acad Sci, Wuhan Inst Phys & Math, Wuhan, Peoples R China |
推荐引用方式 GB/T 7714 | Tang, Ying,Suzuki, Yoshi-ichi,Shen, Huan,et al. Time-resolved photoelectron spectroscopy of bulk liquids at ultra-low kinetic energy[J]. CHEMICAL PHYSICS LETTERS,2010,494(1-3):111-116. |
APA | Tang, Ying.,Suzuki, Yoshi-ichi.,Shen, Huan.,Sekiguchi, Kentaro.,Kurahashi, Naoya.,...&Suzuki, Toshinori.(2010).Time-resolved photoelectron spectroscopy of bulk liquids at ultra-low kinetic energy.CHEMICAL PHYSICS LETTERS,494(1-3),111-116. |
MLA | Tang, Ying,et al."Time-resolved photoelectron spectroscopy of bulk liquids at ultra-low kinetic energy".CHEMICAL PHYSICS LETTERS 494.1-3(2010):111-116. |
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