Coverage-Dependent Structures of Cobalt-Phthalocyanine Molecules Adsorbed on Cu(001) Surface | |
Guo, Qinmin1,2; Qin, Zhihui1; Zang, Kan1,2; Liu, Cunding1,2; Yu, Yinghui1; Cao, Gengyu1 | |
刊名 | LANGMUIR
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2010-07-20 | |
卷号 | 26期号:14页码:11804-11808 |
产权排序 | 第一 |
英文摘要 | The morphologies, self-assembly structures, and stability of cobalt-phthalocyanines (CoPc) molecules adsorbed on Cu(001) with coverage ranging from 0.2 monolayer (ML) to 1.6 ML are investigated by ultrahigh-vacuum low-temperature scanning tunneling microscopy (UHV LT-STM) at liquid nitrogen temperature. Upon increasing the deposition of CoPc molecules various structures, such as isolated adsorption, quasi-hexagonal structure, root 29 x root 29 structure, are well characterized by the corresponding high-resolution STM images. The CoPc-CoPc intermolecular interaction and CoPc-substrate interfacial interaction dominate the structural evolutions. For the coverage higher than 1 ML, CoPc molecules preferentially locate on top of the molecules underneath and organize into root 58 x root 58 structure. As more and more CoPc molecules adsorb on the first layer, in some root 58 x root 58 regions molecular insertion leads to the formation of the root 29 x root 29 domain to effectively decrease the energy of the whole system. |
学科主题 | 原子分子物理学 |
WOS标题词 | Science & Technology ; Physical Sciences ; Technology |
类目[WOS] | Chemistry, Multidisciplinary ; Chemistry, Physical ; Materials Science, Multidisciplinary |
研究领域[WOS] | Chemistry ; Materials Science |
关键词[WOS] | SCANNING-TUNNELING-MICROSCOPY ; COPPER-PHTHALOCYANINE ; METAL PHTHALOCYANINES ; EPITAXIAL-GROWTH ; AU(111) ; GOLD ; STM ; ADSORPTION ; MONOLAYER ; FILMS |
收录类别 | SCI |
语种 | 英语 |
WOS记录号 | WOS:000279756700031 |
内容类型 | 期刊论文 |
源URL | [http://ir.wipm.ac.cn/handle/112942/2019] ![]() |
专题 | 武汉物理与数学研究所_2011年以前论文发表(包括2011年) |
作者单位 | 1.Chinese Acad Sci, Wuhan Inst Phys & Math, State Key Lab Magnet Resonance & Atom & Mol Phys, Wuhan 430071, Peoples R China 2.Chinese Acad Sci, Grad Sch, Beijing 100049, Peoples R China |
推荐引用方式 GB/T 7714 | Guo, Qinmin,Qin, Zhihui,Zang, Kan,et al. Coverage-Dependent Structures of Cobalt-Phthalocyanine Molecules Adsorbed on Cu(001) Surface[J]. LANGMUIR,2010,26(14):11804-11808. |
APA | Guo, Qinmin,Qin, Zhihui,Zang, Kan,Liu, Cunding,Yu, Yinghui,&Cao, Gengyu.(2010).Coverage-Dependent Structures of Cobalt-Phthalocyanine Molecules Adsorbed on Cu(001) Surface.LANGMUIR,26(14),11804-11808. |
MLA | Guo, Qinmin,et al."Coverage-Dependent Structures of Cobalt-Phthalocyanine Molecules Adsorbed on Cu(001) Surface".LANGMUIR 26.14(2010):11804-11808. |
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