The Reactivity of Free Radicals in Biomass Char Studied by EPR Spectroscopy
Gao, Xiuzhi; Feng, Jiwen
刊名MINI-REVIEWS IN ORGANIC CHEMISTRY
2011-11-01
卷号8期号:4页码:438-447
关键词EPR Biomass Char Tobacco
产权排序第一
英文摘要In this review, the features of electron paramagnetic resonance (EPR) spectra of biomass chars prepared from single biopolymers (cellulose, pectin, lignin, etc.) to complex plant materials (tobacco) are summarized, and the interaction of biomass chars with air, O-2 and/or H2O as detected by EPR is critically examined. The effects of inorganic components are emphasized for understanding the creation and annihilation of free radicals in biomass chars in the presence of O-2 or air. While the EPR spectra can be difficult to interpret, the interactions observed reflect fundamental processes occurring in biomass chars during pyrolysis and combustion that may affect the chemical composition of biomass conversion products as well as cigarette emission.
学科主题波谱学
WOS标题词Science & Technology ; Physical Sciences
类目[WOS]Chemistry, Organic
研究领域[WOS]Chemistry
关键词[WOS]ELECTRON-SPIN-RESONANCE ; CARBONIZED ORGANIC POLYMERS ; CELLULOSE PYROLYSIS ; AROMATIC-HYDROCARBONS ; INORGANIC ADDITIVES ; C-13 CPMAS ; TOBACCO ; OXYGEN ; OXIDATION ; MODEL
收录类别SCI
语种英语
WOS记录号WOS:000298495000012
内容类型期刊论文
源URL[http://ir.wipm.ac.cn/handle/112942/1911]  
专题武汉物理与数学研究所_2011年以前论文发表(包括2011年)
作者单位Chinese Acad Sci, State Key Lab Magnet Resonance & Atom & Mol Phys, Wuhan Inst Phys & Math, Wuhan 430071, Peoples R China
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GB/T 7714
Gao, Xiuzhi,Feng, Jiwen. The Reactivity of Free Radicals in Biomass Char Studied by EPR Spectroscopy[J]. MINI-REVIEWS IN ORGANIC CHEMISTRY,2011,8(4):438-447.
APA Gao, Xiuzhi,&Feng, Jiwen.(2011).The Reactivity of Free Radicals in Biomass Char Studied by EPR Spectroscopy.MINI-REVIEWS IN ORGANIC CHEMISTRY,8(4),438-447.
MLA Gao, Xiuzhi,et al."The Reactivity of Free Radicals in Biomass Char Studied by EPR Spectroscopy".MINI-REVIEWS IN ORGANIC CHEMISTRY 8.4(2011):438-447.
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