Varioxepine A, a 3H-Oxepine-Containing Alkaloid with a New Oxa-Cage from the Marine Algal-Derived Endophytic Fungus Paecilomyces variotii

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	Varioxepine A, a 3H-Oxepine-Containing Alkaloid with a New Oxa-Cage from the Marine Algal-Derived Endophytic Fungus Paecilomyces variotii
	Zhang, Peng1,2 ; Mandi, Attila 3; Li, Xiao-Ming 1; Du, Feng-Yu 1; Wang, Jia-Ning1,2 ; Li, Xin1,2 ; Kurtan, Tibor 3; Wang, Bin-Gui1
刊名	ORGANIC LETTERS
	2014-09-19
卷号	16 期号:18 页码:4834-4837
通讯作者	Kurtan, T (reprint author), Debrecen Univ Med, Dept Organ Chem, POB 20, H-4010 Debrecen, Hungary.
英文摘要	A new 3H-oxepine-containing alkaloid, varioxepine A (1), characterized by a structurally unprecedented condensed 3,6,8-trioxabicyclo[3.2.1]octane motif, was isolated from the marine algal-derived endophytic fungus Paecilomyces variotii. Due to the low proton/carbon ratio, the unambiguous assignment of the planar structure and relative configuration was precluded by NMR experiments and solved by single crystal X-ray analysis. The absolute configuration was established by DFT conformational analysis and TDDFT-ECD calculations. Compound 1 inhibited plant pathogenic fungus Fusarium graminearum.
学科主题	Chemistry
收录类别	SCI ; IC
语种	英语
WOS记录号	WOS:000342117600036
内容类型	期刊论文
源URL	[http://ir.qdio.ac.cn/handle/337002/24191]
专题	海洋研究所_实验海洋生物学重点实验室
作者单位	1.Chinese Acad Sci, Inst Oceanol, Key Lab Expt Marine Biol, Qingdao 266071, Peoples R China 2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China 3.Debrecen Univ Med, Dept Organ Chem, H-4010 Debrecen, Hungary
推荐引用方式 GB/T 7714	Zhang, Peng,Mandi, Attila,Li, Xiao-Ming,et al. Varioxepine A, a 3H-Oxepine-Containing Alkaloid with a New Oxa-Cage from the Marine Algal-Derived Endophytic Fungus Paecilomyces variotii[J]. ORGANIC LETTERS,2014,16(18):4834-4837.
APA	Zhang, Peng.,Mandi, Attila.,Li, Xiao-Ming.,Du, Feng-Yu.,Wang, Jia-Ning.,...&Wang, Bin-Gui.(2014).Varioxepine A, a 3H-Oxepine-Containing Alkaloid with a New Oxa-Cage from the Marine Algal-Derived Endophytic Fungus Paecilomyces variotii.ORGANIC LETTERS,16(18),4834-4837.
MLA	Zhang, Peng,et al."Varioxepine A, a 3H-Oxepine-Containing Alkaloid with a New Oxa-Cage from the Marine Algal-Derived Endophytic Fungus Paecilomyces variotii".ORGANIC LETTERS 16.18(2014):4834-4837.