Organic micropollutants in the Yangtze River: Seasonal occurrence and annual loads

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	Organic micropollutants in the Yangtze River: Seasonal occurrence and annual loads
	Qi, Webdao ; Mueller, Beat ; Pernet-Coudrier, Benoit ; Singer, Heinz ; Liu, Huijuan ; Qu, Jiuhui ; Berg, Michael
刊名	SCIENCE OF THE TOTAL ENVIRONMENT
	2014
卷号	472 期号:1 页码:789-799
关键词	Yangtze River Organic micropollutants Pharmaceuticals Pesticides Household chemicals Polycyclic aromatic hydrocarbons
ISSN号	0048-9697
中文摘要	Twenty percent of the water run-off from China's land surface drains into the Yangtze River and carries the sewage of approximately 400 million people out to sea. The lower stretch of the Yangtze therefore offers the opportunity to assess the pollutant discharge of a huge population. To establish a comprehensive assessment of micropollutants, river water samples were collected monthly from May 2009 to June 2010 along a cross-section at the lowermost hydrological station of the Yangtze River not influenced by the tide (Datong Station, Anhui province). Following a prescreening of 268 target compounds, we examined the occurrence, seasonal variation, and annual loads of 117 organic micropollutants, including 51 pesticides, 43 pharmaceuticals, 7 household and industrial chemicals, and 16 polycyclic aromatic hydrocarbons (PAHs). During the 14-month study, the maximum concentrations of particulate PAHs (1-5 mu g/g), pesticides (11-284 ng/L), pharmaceuticals (5-224 ng/L), and household and industrial chemicals (4-430 ng/L) were generally lower than in other Chinese rivers due to the dilution caused of the Yangtze River's average water discharge of approximately 30,000 m(3)/s. The loads of most pesticides, anti-infectives, and PAHs were higher in the wet season compared to the dry season, which was attributed to the increased agricultural application of chemicals in the summer, an elevated water discharge through the sewer systems and wastewater treatment plants (WWTP) as a result of high hydraulic loads and the related lower treatment efficiency, and seasonally increased deposition from the atmosphere and runoff from the catchment. The estimated annual load of PAHs in the river accounted for some 4% of the total emission of PAHs in the whole Yangtze Basin. Furthermore, by using sucralose as a tracer for domestic wastewater, we estimate a daily disposal of approximately 47 million m(3) of sewage into the river, corresponding to 1.8% of its average hydraulic load. In summary, the annual amounts flushed by the Yangtze River into the East China Sea were 2.9 x 10(6) tons of dissolved and particulate organic carbon (DOC and POC), 369 tons of PAHs, 98 tons of pesticides, 152 tons of pharmaceuticals, and 273 tons of household and industrial chemicals. While the concentrations seem comparably moderate, the pollutant loads are considerable and pose an increasing burden to the health of the marine coastal ecosystem. (C) 2013 Elsevier B.V. All rights reserved.
WOS记录号	WOS:000331916100086
公开日期	2015-03-26
内容类型	期刊论文
源URL	[http://ir.rcees.ac.cn/handle/311016/9576]
专题	生态环境研究中心_环境水质学国家重点实验室
推荐引用方式 GB/T 7714	Qi, Webdao,Mueller, Beat,Pernet-Coudrier, Benoit,et al. Organic micropollutants in the Yangtze River: Seasonal occurrence and annual loads[J]. SCIENCE OF THE TOTAL ENVIRONMENT,2014,472(1):789-799.
APA	Qi, Webdao.,Mueller, Beat.,Pernet-Coudrier, Benoit.,Singer, Heinz.,Liu, Huijuan.,...&Berg, Michael.(2014).Organic micropollutants in the Yangtze River: Seasonal occurrence and annual loads.SCIENCE OF THE TOTAL ENVIRONMENT,472(1),789-799.
MLA	Qi, Webdao,et al."Organic micropollutants in the Yangtze River: Seasonal occurrence and annual loads".SCIENCE OF THE TOTAL ENVIRONMENT 472.1(2014):789-799.