Characterization and identification of chemical components in Neopicrorhiza scrphulariiflora roots by liquid chromatography-electrospray ionization quadrupole time-of-flight tandem mass spectrometry | |
Li, Chunting1,3; Liu, Yongqiang2; Abdulla, Rahima2; Aisa, Haji Akber2; Suo, Yourui1 | |
刊名 | analytical methods |
2014-06-07 | |
卷号 | 6期号:11页码:3634-3643 |
ISSN号 | 1759-9660 |
中文摘要 | liquid chromatography-electrospray ionization quadrupole time-of-flight tandem mass spectrometry (lc-esi-qtof-ms) was applied to identify chemical components occurring in neopicrorhiza scrphulariiflora roots. 24 compounds, including 12 iridoid glycosides, 3 phenyl glycosides and 9 phenylethanoid glycosides, were detected and tentatively characterized according to accurate mass measurements and their characteristic fragmentation at low and high collision energy. meanwhile, appropriate fragmentation pathways were proposed based on definite composition of the product ions. 6'-o-feruloyl-3,4-dihydrocatalpol and 1-[2-(4-(3,4-dihydroxycinnamoyl)-3-glucosyl)glucosy]ethy-3-hydroxy-4-methoxybenzene are potentially novel compounds. 6'-o-caffeoylcatalpol and maxoside were characterized in n. scrphulariiflora for the first time. this study established that the lc-esi-qtof-ms method is efficient for identifying, and could be the basis for the comprehensive quality control of, n. scrphulariiflora roots. |
英文摘要 | liquid chromatography-electrospray ionization quadrupole time-of-flight tandem mass spectrometry (lc-esi-qtof-ms) was applied to identify chemical components occurring in neopicrorhiza scrphulariiflora roots. 24 compounds, including 12 iridoid glycosides, 3 phenyl glycosides and 9 phenylethanoid glycosides, were detected and tentatively characterized according to accurate mass measurements and their characteristic fragmentation at low and high collision energy. meanwhile, appropriate fragmentation pathways were proposed based on definite composition of the product ions. 6'-o-feruloyl-3,4-dihydrocatalpol and 1-[2-(4-(3,4-dihydroxycinnamoyl)-3-glucosyl)glucosy]ethy-3-hydroxy-4-methoxybenzene are potentially novel compounds. 6'-o-caffeoylcatalpol and maxoside were characterized in n. scrphulariiflora for the first time. this study established that the lc-esi-qtof-ms method is efficient for identifying, and could be the basis for the comprehensive quality control of, n. scrphulariiflora roots. |
WOS标题词 | science & technology ; physical sciences ; life sciences & biomedicine ; technology |
类目[WOS] | chemistry, analytical ; food science & technology ; spectroscopy |
研究领域[WOS] | chemistry ; food science & technology ; spectroscopy |
关键词[WOS] | picrorhiza-scrophulariiflora ; phenylethanoid glycosides ; structural-characterization ; phenylpropanoid glycosides ; flavonoid glycosides ; iridoid glucosides ; multistage ; fragmentation ; phenyl |
收录类别 | SCI |
语种 | 英语 |
WOS记录号 | WOS:000336820300015 |
公开日期 | 2014-12-19 |
内容类型 | 期刊论文 |
源URL | [http://ir.nwipb.ac.cn/handle/363003/4221] |
专题 | 西北高原生物研究所_中国科学院西北高原生物研究所 |
作者单位 | 1.Chinese Acad Sci, Northwest Inst Plateau Biol, Key Lab Tibetan Med Res, Xining 810008, Peoples R China 2.Chinese Acad Sci, Xinjiang Tech Inst Phys & Chem, Key Lab Plant Resources & Chem Arid Reg, Urumqi 830011, Peoples R China 3.Univ Chinese Acad Sci, Beijing 100049, Peoples R China |
推荐引用方式 GB/T 7714 | Li, Chunting,Liu, Yongqiang,Abdulla, Rahima,et al. Characterization and identification of chemical components in Neopicrorhiza scrphulariiflora roots by liquid chromatography-electrospray ionization quadrupole time-of-flight tandem mass spectrometry[J]. analytical methods,2014,6(11):3634-3643. |
APA | Li, Chunting,Liu, Yongqiang,Abdulla, Rahima,Aisa, Haji Akber,&Suo, Yourui.(2014).Characterization and identification of chemical components in Neopicrorhiza scrphulariiflora roots by liquid chromatography-electrospray ionization quadrupole time-of-flight tandem mass spectrometry.analytical methods,6(11),3634-3643. |
MLA | Li, Chunting,et al."Characterization and identification of chemical components in Neopicrorhiza scrphulariiflora roots by liquid chromatography-electrospray ionization quadrupole time-of-flight tandem mass spectrometry".analytical methods 6.11(2014):3634-3643. |
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