Ordered mesoporous zirconium oxophosphate supported tungsten oxide solid acid catalysts: the improved Bronsted acidity for benzylation of anisole | |
Miao ZC(苗智超)1,2; Zhao HH(赵华华)1; Song HL(宋焕玲)1,3; Chou LJ(丑凌军)1,3; Chou LJ(丑凌军) | |
刊名 | RSC Advances |
2014 | |
卷号 | 4期号:43页码:22509-22519 |
ISSN号 | 2046-2069 |
通讯作者 | 丑凌军 |
英文摘要 | A series of WO3 supported on ordered mesoporous zirconium oxophosphate (X wt% WO3/M-ZrPO) solid acid catalysts with a WO3 loading from 5 to 30 wt% were successfully synthesized, and their structure properties were characterized by X-ray diffraction (XRD), Raman spectroscopy, N2-physisorption, transmission electron microscopy (TEM), UV-visible diffuse reflectance spectroscopy, Fourier transform infrared (FT-IR) spectroscopy, H2 temperature-programmed reduction (H2-TPR) and X-ray photoelectron spectroscopy (XPS). The catalytic performance of X wt% WO3/M-ZrPO in liquid phase benzylation of anisole was studied and the relation between activity and states of tungsten species was investigated detailedly. The maximum catalytic activity was reached at a 20 wt% WO3 loading, which possessed highly dispersed WO3 species and the strongest Brønsted acidity. Meanwhile, the well dispersed WO3 species strongly interacted with M-ZrPO, therefore, both sintering and leaching of WO3 species were effectively restrained. Moreover, compared with the traditional zirconium phosphate synthesized from the sol–gel method (ZrPsol–gel), the M-ZrPO with an abundant ordered mesostructure was propitious for improving the dispersion of WO3 species and catalytic performance. In addition, the 20 wt% WO3/M-ZrPO showed a markedly higher catalytic activity than H-ZSM5, H-Beta and 20 wt% WO3/ZrPsol–gel. Furthermore, the catalyst showed no discernible loss in activity or selectivity after five cycles. |
学科主题 | 物理化学与绿色催化 |
收录类别 | SCI |
资助信息 | the National Basic Research Program of PR China (no. 2011CB201404) and the National Natural Science Foundation of China (no. 21133011) |
语种 | 英语 |
WOS记录号 | WOS:000337124900030 |
公开日期 | 2014-11-20 |
内容类型 | 期刊论文 |
源URL | [http://210.77.64.217/handle/362003/6724] |
专题 | 兰州化学物理研究所_OSSO国家重点实验室 |
通讯作者 | Chou LJ(丑凌军) |
作者单位 | 1.Chinese Acad Sci, Lanzhou Inst Chem Phys, State Key Lab Oxo Synth & Select Oxidat, Lanzhou 730000, Peoples R China 2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China 3.Chinese Acad Sci, Suzhou Inst Nanotech & Nanobion, Suzhou 215123, Peoples R China |
推荐引用方式 GB/T 7714 | Miao ZC,Zhao HH,Song HL,et al. Ordered mesoporous zirconium oxophosphate supported tungsten oxide solid acid catalysts: the improved Bronsted acidity for benzylation of anisole[J]. RSC Advances,2014,4(43):22509-22519. |
APA | Miao ZC,Zhao HH,Song HL,Chou LJ,&丑凌军.(2014).Ordered mesoporous zirconium oxophosphate supported tungsten oxide solid acid catalysts: the improved Bronsted acidity for benzylation of anisole.RSC Advances,4(43),22509-22519. |
MLA | Miao ZC,et al."Ordered mesoporous zirconium oxophosphate supported tungsten oxide solid acid catalysts: the improved Bronsted acidity for benzylation of anisole".RSC Advances 4.43(2014):22509-22519. |
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