Slice imaging of methyl bromide photofragmentation at 193 nm

	Slice imaging of methyl bromide photofragmentation at 193 nm
	Wang, Fengyan 1,2; Lipciuc, M. Laura 1; Kartakoullis, Andreas 1,4; Glodic, Pavle 1,4; Samartzis, Peter C.1; Yang, Xueming 3; Kitsopoulos, Theofanis N.1,4
刊名	physical chemistry chemical physics
	2014
卷号	16 期号:2 页码:599-606
通讯作者	theofanis n. kitsopoulos
产权排序	待补充
合作状况	英
英文摘要	the photodissociation of methyl bromide at 193 nm is studied using slice imaging. from the measured photofragment translational energy and angular distributions we were able to extract methyl-state-specific dissociation channel yields and crossing probabilities between (3)q(0) and (1)q(1) surfaces. the angular distributions for the bromine photofragments show a strong dependence on the total translational energy release. nonadiabatic transition probabilities from the (3)q(0) to (1)q(1) surface dominate the dynamics in this excitation energy region and for most of the methyl vibrational states probed.
学科主题	物理化学
WOS标题词	science & technology ; physical sciences
类目[WOS]	chemistry, physical ; physics, atomic, molecular & chemical
研究领域[WOS]	chemistry ; physics
关键词[WOS]	multiphoton ionization spectroscopy ; a-band ; photodissociation ; alignment ; ch3br ; excitation ; molecules ; dynamics ; rotation ; initio
收录类别	SCI
资助信息	3，6
原文出处	606
语种	英语
WOS记录号	WOS:000327888100025
公开日期	2014-09-11
内容类型	期刊论文
源URL	[http://159.226.238.44/handle/321008/119759]
专题	大连化学物理研究所_中国科学院大连化学物理研究所
作者单位	1.Fdn Res & Technol Hellas, Inst Elect Struct & Laser, Iraklion 71110, Greece 2.Fudan Univ, Dept Chem, Shanghai 200433, Peoples R China 3.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Mol React Dynam, Dalian 116023, Peoples R China 4.Univ Crete, Dept Chem, Iraklion 71003, Greece
推荐引用方式 GB/T 7714	Wang, Fengyan,Lipciuc, M. Laura,Kartakoullis, Andreas,et al. Slice imaging of methyl bromide photofragmentation at 193 nm[J]. physical chemistry chemical physics,2014,16(2):599-606.
APA	Wang, Fengyan.,Lipciuc, M. Laura.,Kartakoullis, Andreas.,Glodic, Pavle.,Samartzis, Peter C..,...&Kitsopoulos, Theofanis N..(2014).Slice imaging of methyl bromide photofragmentation at 193 nm.physical chemistry chemical physics,16(2),599-606.
MLA	Wang, Fengyan,et al."Slice imaging of methyl bromide photofragmentation at 193 nm".physical chemistry chemical physics 16.2(2014):599-606.