Heat capacities and thermodynamic properties of Ni-9(btz)(12)(DMA)(6)(NO3)(6)

	Heat capacities and thermodynamic properties of Ni-9(btz)(12)(DMA)(6)(NO3)(6)
	Zhou, Yi-Xi 1,2; Sun, Li-Xian 1; Cao, Zhong 2; Xu, Fen 3; Jiang, Chun-Hong 1; Jiao, Cheng-Li 1; Zhang, Hui 1,2; Zhang, Jian 1; Zhou, Huai-Ying 4; Li, Fen 1
刊名	journal of thermal analysis and calorimetry
	2013-02-01
卷号	111 期号:2 页码:1603-1608
关键词	Crystalline Molar heat capacity TG TMDSC
通讯作者	孙立贤
产权排序	待补充
合作状况	英
英文摘要	the low-temperature molar heat capacity of crystalline ni-9(btz)(12)(dma)(6)(no3)(6) (1) (btz = benzotriazolate; dma = n,n'-dimethylacetamide) was measured by temperature-modulated differential scanning calorimetry for the first time. the thermodynamic parameters such as entropy and enthalpy relative to reference temperature 298.15 k were obtained based on the above molar heat capacity data. the compound was synthesized by solvothermal method and characterized by powder x-ray diffraction and ft-ir spectra. moreover, the thermal stability and the decomposition mechanism of ni-9(btz)(12)(dma)(6)(no3)(6) were investigated by thermogravimetry (tg) analysis under air atmosphere from 300 to 873 k. the experimental results through tg measurement demonstrate that the compound has a two-stage mass loss in air flow.
学科主题	物理化学
WOS标题词	science & technology ; physical sciences
类目[WOS]	chemistry, analytical ; chemistry, physical
研究领域[WOS]	chemistry
关键词[WOS]	storage materials ; dsc ; nanostructures ; temperature ; polymer
收录类别	SCI
资助信息	1，1
原文出处	1608
语种	英语
WOS记录号	WOS:000313409700077
公开日期	2014-09-11
内容类型	期刊论文
源URL	[http://159.226.238.44/handle/321008/119236]
专题	大连化学物理研究所_中国科学院大连化学物理研究所
作者单位	1.Chinese Acad Sci, Dalian Inst Chem Phys, Mat & Thermochem Lab, Dalian 116023, Peoples R China 2.Changsha Univ Sci & Technol, Sch Chem & Biol Engn, Changsha 410004, Hunan, Peoples R China 3.Liaoning Normal Univ, Fac Chem & Chem Engn, Dalian 116029, Peoples R China 4.Guilin Univ Elect Technol, Dept Mat Sci & Engn, Guilin 541004, Peoples R China
推荐引用方式 GB/T 7714	Zhou, Yi-Xi,Sun, Li-Xian,Cao, Zhong,et al. Heat capacities and thermodynamic properties of Ni-9(btz)(12)(DMA)(6)(NO3)(6)[J]. journal of thermal analysis and calorimetry,2013,111(2):1603-1608.
APA	Zhou, Yi-Xi.,Sun, Li-Xian.,Cao, Zhong.,Xu, Fen.,Jiang, Chun-Hong.,...&Zhang, Huang-Zhi.(2013).Heat capacities and thermodynamic properties of Ni-9(btz)(12)(DMA)(6)(NO3)(6).journal of thermal analysis and calorimetry,111(2),1603-1608.
MLA	Zhou, Yi-Xi,et al."Heat capacities and thermodynamic properties of Ni-9(btz)(12)(DMA)(6)(NO3)(6)".journal of thermal analysis and calorimetry 111.2(2013):1603-1608.