Pulse radiolysis and laser flash photolysis study of balofloxacin | |
Xu Yulie ; Liu Yancheng ; Li Haixia ; Zhang Peng ; Tang Ruizhi ; Cao Xiyan ; Wang Wenfeng | |
刊名 | NUCLEAR SCIENCE AND TECHNIQUES |
2013 | |
卷号 | 24 |
ISSN号 | 1001-8042 |
英文摘要 | Pulse radiolysis studies of the reactions between balofloxacin (BFX) and e(aq)(-), hydroxyl radical ((OH)-O-.), and N-3(.) were carried out to investigate the photosensitive toxicity of BFX. The BFX radical anion formed in the reaction of BFX with e(aq)(-) was located at 380 nm. The transient species formed in the reaction of BFX with (OH)-O-. radical were located in the region of 370 rim to 580 rim, with a maximum lambda(max) at 390 rim. The BFX radical cation was obtained by reacting BFX with N-3(.), and showed an absorption band at around 365 nm. The UV-Vis absorption of the BFX was found to be clearly dependent on pH. The pK(a) value of BFX was estimated to be 6.0 +/- 0.2. Under neutral conditions, the rate constants of BFX reacting with N-3(.) and e(aq)(-) were determined to be 1.3x10(10) dm(3.)mol(-1).s(-1) and 1.4x10(10) dm(3).mol(-1.)s(-1), respectively. |
收录类别 | SCI |
语种 | 英语 |
WOS记录号 | WOS:000333376800015 |
公开日期 | 2014-06-13 |
内容类型 | 期刊论文 |
源URL | [http://ir.sinap.ac.cn/handle/331007/13873] |
专题 | 上海应用物理研究所_中科院上海应用物理研究所2011-2017年 |
推荐引用方式 GB/T 7714 | Xu Yulie,Liu Yancheng,Li Haixia,et al. Pulse radiolysis and laser flash photolysis study of balofloxacin[J]. NUCLEAR SCIENCE AND TECHNIQUES,2013,24. |
APA | Xu Yulie.,Liu Yancheng.,Li Haixia.,Zhang Peng.,Tang Ruizhi.,...&Wang Wenfeng.(2013).Pulse radiolysis and laser flash photolysis study of balofloxacin.NUCLEAR SCIENCE AND TECHNIQUES,24. |
MLA | Xu Yulie,et al."Pulse radiolysis and laser flash photolysis study of balofloxacin".NUCLEAR SCIENCE AND TECHNIQUES 24(2013). |
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