Synthesis of the end-functionalized polymethyl methacrylate incorporated with an asymmetrical porphyrin group via atom transfer radical polymerization and investigation on the third-order nonlinear optical properties

CORC > 长春光学精密机械与物理研究所 > 中国科学院长春光学精密机械与物理研究所 > 中科院长春光机所知识产出

	Synthesis of the end-functionalized polymethyl methacrylate incorporated with an asymmetrical porphyrin group via atom transfer radical polymerization and investigation on the third-order nonlinear optical properties
	Qiu N. N. ; Liu D. J. ; Han S. L. ; He X. Q. ; Cui G. H. ; Duan Q.
刊名	Journal of Photochemistry and Photobiology a-Chemistry
	2013
期号	272
ISSN号	ISBN/1010-6030
英文摘要	A novel asymmetrical zinc(II) porphyrin (ZnPor-Br) was synthesized as the initiator for the atom transfer radical polymerization (ATRP). Using CuBr/2,2'-dipyridyl as the catalyst system, the ATRP of polymethyl methacrylate (PMMA) was carried out to afford a new linear PMMA with the end group of the asymmetrical porphyrin (ZnPor-PMMA). The structures of the porphyrin, ZnPor-Br and as-prepared polymer were determined by FT-IR, H-1 NMR spectra and further confirmed by element analysis. Polydispersity index (PDI) obtaining from the gel permeation chromatograph (GPC) indicated that the molecular weight distribution was narrow, and the whole process of polymerization was well controlled. The third-order nonlinear optical properties of polymers were investigated by using Z-scan technique in the pico-second time scale. The nonlinear refracting index (n(2)) and the third-order nonlinear polarizability [chi((3))] were 4.1 x 10(-10) esu and 1.64 x 10(-10) esu respectively, while the molecular polarizability (gamma') was 1.01 x 10(-28) esu (M-n = 2000). The obtained results implied that the prepared compound featured the large nonlinear optical limiting properties and could serve as a potential candidate for the reverse saturable absorption (RSA) and the refractive-based optical limiting applications in the laser protection field. (C) 2013 Elsevier B.V. All rights reserved.
收录类别	SCI
公开日期	2014-05-14
内容类型	期刊论文
源URL	[http://ir.ciomp.ac.cn/handle/181722/40886]
专题	长春光学精密机械与物理研究所_中科院长春光机所知识产出
推荐引用方式 GB/T 7714	Qiu N. N.,Liu D. J.,Han S. L.,et al. Synthesis of the end-functionalized polymethyl methacrylate incorporated with an asymmetrical porphyrin group via atom transfer radical polymerization and investigation on the third-order nonlinear optical properties[J]. Journal of Photochemistry and Photobiology a-Chemistry,2013(272).
APA	Qiu N. N.,Liu D. J.,Han S. L.,He X. Q.,Cui G. H.,&Duan Q..(2013).Synthesis of the end-functionalized polymethyl methacrylate incorporated with an asymmetrical porphyrin group via atom transfer radical polymerization and investigation on the third-order nonlinear optical properties.Journal of Photochemistry and Photobiology a-Chemistry(272).
MLA	Qiu N. N.,et al."Synthesis of the end-functionalized polymethyl methacrylate incorporated with an asymmetrical porphyrin group via atom transfer radical polymerization and investigation on the third-order nonlinear optical properties".Journal of Photochemistry and Photobiology a-Chemistry .272(2013).