On Off On Fluorescent Carbon Dot Nanosensor for Recognition of Chromium(VI) and Ascorbic Acid Based on the Inner Filter Effect
Zheng M. ; Xie Z. G. ; Qu D. ; Li D. ; Du P. ; Jing X. B. ; Sun Z. C.
刊名Acs Applied Materials & Interfaces
2013
卷号5期号:24
ISSN号ISBN/1944-8244
英文摘要Chromium(VI) [Cr(VI)] is considered as a severe environmental pollutant, due to its highly toxic and carcinogenic properties. Therefore, low cost, highly sensitive sensors for the determination of Cr(VI) are highly demanded. It is well-known that highly luminescent carbon dots (CDs) have been successfully applied as fluorescent nanosensors for pH, ions, and molecular substances. In the present work, we have demonstrated an on-off fluorescent CD probe for detecting Cr(VI) based on the inner filter effect (IFE) because the absorption bands of Cr(IV) fully covered the emission and excitation bands of CDs. This CD-based nanosensor provides obvious advantages of simplicity, convenience, rapid response, high selectivity, and sensitivity, which have potential application for the detection of Cr(VI) in the environmental industry. In addition, because Cr(VI) can be reduced to low valent chromium species easily by reductant, resulting in the elimination of the WE and recovery of CD fluorescence, the CD-Cr(VI) mixture could behave as an off-on type fluorescent probe for reductant. We employed ascorbic acid (AA) as an example molecule to demonstrate this off-on type fluorescent probe.
收录类别SCI
语种internal-pdf://3885792911/ome-3-8-1187.pdf
公开日期2014-05-14
内容类型期刊论文
源URL[http://ir.ciomp.ac.cn/handle/181722/40789]  
专题长春光学精密机械与物理研究所_中科院长春光机所知识产出
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Zheng M.,Xie Z. G.,Qu D.,et al. On Off On Fluorescent Carbon Dot Nanosensor for Recognition of Chromium(VI) and Ascorbic Acid Based on the Inner Filter Effect[J]. Acs Applied Materials & Interfaces,2013,5(24).
APA Zheng M..,Xie Z. G..,Qu D..,Li D..,Du P..,...&Sun Z. C..(2013).On Off On Fluorescent Carbon Dot Nanosensor for Recognition of Chromium(VI) and Ascorbic Acid Based on the Inner Filter Effect.Acs Applied Materials & Interfaces,5(24).
MLA Zheng M.,et al."On Off On Fluorescent Carbon Dot Nanosensor for Recognition of Chromium(VI) and Ascorbic Acid Based on the Inner Filter Effect".Acs Applied Materials & Interfaces 5.24(2013).
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