A new synthetic route to hollow Co3O4 octahedra for supercapacitor applications
Cao, Yuebin1; Yuan, Fangli2; Yao, Mingshui2; Bang, Jin Ho3,4; Lee, Jung-Ho1
刊名CRYSTENGCOMM
2014
卷号16期号:5页码:826-833
关键词high-performance supercapacitor lithium storage properties carbon-fiber paper electrochemical capacitors nanowire arrays ni foam growth fabrication spheres oxyhydroxide
ISSN号1466-8033
其他题名Crystengcomm
中文摘要Co3O4 hollow octahedra were successfully synthesized via a facile one-step solvothermal route. Time-resolved electron microscopy and X-ray diffraction analyses revealed that the Co3O4 hollow octahedra were formed through the self-assembly of primary nanocrystals followed by subsequent Ostwald ripening. Subtle control over the reaction conditions led to different morphologies (hexagonal plates and nanocubes) and crystal structures (beta-Co(OH)(2)-Co3O4 composite). The unique hollow nanostructure rendered our Co3O4 potentially useful for charge-storage applications. To prove its usefulness, the pseudocapacitive performance of the Co3O4 hollow octahedra as a supercapacitor electrode was evaluated and exhibited a charge storage capacity of 192 F g(-1) with good long-term cyclability.
英文摘要Co3O4 hollow octahedra were successfully synthesized via a facile one-step solvothermal route. Time-resolved electron microscopy and X-ray diffraction analyses revealed that the Co3O4 hollow octahedra were formed through the self-assembly of primary nanocrystals followed by subsequent Ostwald ripening. Subtle control over the reaction conditions led to different morphologies (hexagonal plates and nanocubes) and crystal structures (beta-Co(OH)(2)-Co3O4 composite). The unique hollow nanostructure rendered our Co3O4 potentially useful for charge-storage applications. To prove its usefulness, the pseudocapacitive performance of the Co3O4 hollow octahedra as a supercapacitor electrode was evaluated and exhibited a charge storage capacity of 192 F g(-1) with good long-term cyclability.
WOS标题词Science & Technology ; Physical Sciences
类目[WOS]Chemistry, Multidisciplinary ; Crystallography
研究领域[WOS]Chemistry ; Crystallography
关键词[WOS]HIGH-PERFORMANCE SUPERCAPACITOR ; LITHIUM STORAGE PROPERTIES ; CARBON-FIBER PAPER ; ELECTROCHEMICAL CAPACITORS ; NANOWIRE ARRAYS ; NI FOAM ; GROWTH ; FABRICATION ; SPHERES ; OXYHYDROXIDE
收录类别SCI
原文出处://WOS:000328952000012
语种英语
WOS记录号WOS:000328952000012
公开日期2014-05-06
内容类型期刊论文
版本出版稿
源URL[http://ir.ipe.ac.cn/handle/122111/8147]  
专题过程工程研究所_研究所(批量导入)
作者单位1.Hanyang Univ, Dept Chem Engn, Ansan 426791, South Korea
2.Chinese Acad Sci, Inst Proc Engn, State Key Lab Multiphase Complex Syst, Beijing 100190, Peoples R China
3.Hanyang Univ, Dept Chem & Appl Chem, Ansan 426791, South Korea
4.Hanyang Univ, Dept Bionano Engn, Ansan 426791, South Korea
推荐引用方式
GB/T 7714
Cao, Yuebin,Yuan, Fangli,Yao, Mingshui,et al. A new synthetic route to hollow Co3O4 octahedra for supercapacitor applications[J]. CRYSTENGCOMM,2014,16(5):826-833.
APA Cao, Yuebin,Yuan, Fangli,Yao, Mingshui,Bang, Jin Ho,&Lee, Jung-Ho.(2014).A new synthetic route to hollow Co3O4 octahedra for supercapacitor applications.CRYSTENGCOMM,16(5),826-833.
MLA Cao, Yuebin,et al."A new synthetic route to hollow Co3O4 octahedra for supercapacitor applications".CRYSTENGCOMM 16.5(2014):826-833.
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