A new synthetic route to hollow Co3O4 octahedra for supercapacitor applications | |
Cao, Yuebin1; Yuan, Fangli2; Yao, Mingshui2; Bang, Jin Ho3,4; Lee, Jung-Ho1 | |
刊名 | CRYSTENGCOMM |
2014 | |
卷号 | 16期号:5页码:826-833 |
关键词 | high-performance supercapacitor lithium storage properties carbon-fiber paper electrochemical capacitors nanowire arrays ni foam growth fabrication spheres oxyhydroxide |
ISSN号 | 1466-8033 |
其他题名 | Crystengcomm |
中文摘要 | Co3O4 hollow octahedra were successfully synthesized via a facile one-step solvothermal route. Time-resolved electron microscopy and X-ray diffraction analyses revealed that the Co3O4 hollow octahedra were formed through the self-assembly of primary nanocrystals followed by subsequent Ostwald ripening. Subtle control over the reaction conditions led to different morphologies (hexagonal plates and nanocubes) and crystal structures (beta-Co(OH)(2)-Co3O4 composite). The unique hollow nanostructure rendered our Co3O4 potentially useful for charge-storage applications. To prove its usefulness, the pseudocapacitive performance of the Co3O4 hollow octahedra as a supercapacitor electrode was evaluated and exhibited a charge storage capacity of 192 F g(-1) with good long-term cyclability. |
英文摘要 | Co3O4 hollow octahedra were successfully synthesized via a facile one-step solvothermal route. Time-resolved electron microscopy and X-ray diffraction analyses revealed that the Co3O4 hollow octahedra were formed through the self-assembly of primary nanocrystals followed by subsequent Ostwald ripening. Subtle control over the reaction conditions led to different morphologies (hexagonal plates and nanocubes) and crystal structures (beta-Co(OH)(2)-Co3O4 composite). The unique hollow nanostructure rendered our Co3O4 potentially useful for charge-storage applications. To prove its usefulness, the pseudocapacitive performance of the Co3O4 hollow octahedra as a supercapacitor electrode was evaluated and exhibited a charge storage capacity of 192 F g(-1) with good long-term cyclability. |
WOS标题词 | Science & Technology ; Physical Sciences |
类目[WOS] | Chemistry, Multidisciplinary ; Crystallography |
研究领域[WOS] | Chemistry ; Crystallography |
关键词[WOS] | HIGH-PERFORMANCE SUPERCAPACITOR ; LITHIUM STORAGE PROPERTIES ; CARBON-FIBER PAPER ; ELECTROCHEMICAL CAPACITORS ; NANOWIRE ARRAYS ; NI FOAM ; GROWTH ; FABRICATION ; SPHERES ; OXYHYDROXIDE |
收录类别 | SCI |
原文出处 | |
语种 | 英语 |
WOS记录号 | WOS:000328952000012 |
公开日期 | 2014-05-06 |
内容类型 | 期刊论文 |
版本 | 出版稿 |
源URL | [http://ir.ipe.ac.cn/handle/122111/8147] |
专题 | 过程工程研究所_研究所(批量导入) |
作者单位 | 1.Hanyang Univ, Dept Chem Engn, Ansan 426791, South Korea 2.Chinese Acad Sci, Inst Proc Engn, State Key Lab Multiphase Complex Syst, Beijing 100190, Peoples R China 3.Hanyang Univ, Dept Chem & Appl Chem, Ansan 426791, South Korea 4.Hanyang Univ, Dept Bionano Engn, Ansan 426791, South Korea |
推荐引用方式 GB/T 7714 | Cao, Yuebin,Yuan, Fangli,Yao, Mingshui,et al. A new synthetic route to hollow Co3O4 octahedra for supercapacitor applications[J]. CRYSTENGCOMM,2014,16(5):826-833. |
APA | Cao, Yuebin,Yuan, Fangli,Yao, Mingshui,Bang, Jin Ho,&Lee, Jung-Ho.(2014).A new synthetic route to hollow Co3O4 octahedra for supercapacitor applications.CRYSTENGCOMM,16(5),826-833. |
MLA | Cao, Yuebin,et al."A new synthetic route to hollow Co3O4 octahedra for supercapacitor applications".CRYSTENGCOMM 16.5(2014):826-833. |
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