Construction of porous Mn(II)-based metal-organic frameworks by flexible hexacarboxylic acid and rigid coligands

	Construction of porous Mn(II)-based metal-organic frameworks by flexible hexacarboxylic acid and rigid coligands
	Yi FY ; Dang S ; Yang WT ; Sun ZM
刊名	crystengcomm
	2013
卷号	15 期号:41 页码:8320-8329
关键词	HYDROGEN-BONDED NETWORKS LUMINESCENT PROPERTIES COORDINATION POLYMERS ADSORPTION PROPERTIES MOLECULAR TECTONICS MAGNETIC-PROPERTIES CRYSTAL-STRUCTURES LIGAND COMPLEXES ARCHITECTURES
ISSN号	1466-8033
通讯作者	yi fy
中文摘要	solvothermal reactions of hexa[4-(carboxyphenyl) oxamethyl]-3-oxapentane (h6l) with rigid coligands, 2,2'-bipyridine (bipy), 1,4-bis-(1-imidazolyl) benzene (dib), and 4,4'-bis(1-imidazolyl) biphenyl (bibp) in the presence of manganese salts produce four porous mn(ii) metal-organic frameworks (mn-mofs), namely, mn-3(l)(bipy)(2) (1), mn-3(l)(dib) (2), mn-3(l)(dib)(h2o)(2) (3), and mn-6(l)(2)(bibp)(1.5)(h2o)(5) 4. single crystal x-ray diffraction analyses reveal that 1-4 consist of trinuclear mn-ii subunits, which are further connected into four interesting nets, 4,4-connected pts net for 1, 4,6-connected fsc net for 2, and two novel nets for 3 and 4, by the synergistic effect of carboxylate groups and functionally complementary n-donor ligands. they exhibit high potential solvent accessible volumes of 35.0%, 33.5%, 45.1%, and 56.5% for 1-4, respectively. magnetic studies indicate the presence of weak antiferromagnetic interactions between mn-ii centers in these compounds.
收录类别	SCI收录期刊论文
语种	英语
WOS记录号	WOS:000325368300014
公开日期	2014-04-16
内容类型	期刊论文
源URL	[http://ir.ciac.jl.cn/handle/322003/50178]
专题	长春应用化学研究所_长春应用化学研究所知识产出_期刊论文
推荐引用方式 GB/T 7714	Yi FY,Dang S,Yang WT,et al. Construction of porous Mn(II)-based metal-organic frameworks by flexible hexacarboxylic acid and rigid coligands[J]. crystengcomm,2013,15(41):8320-8329.
APA	Yi FY,Dang S,Yang WT,&Sun ZM.(2013).Construction of porous Mn(II)-based metal-organic frameworks by flexible hexacarboxylic acid and rigid coligands.crystengcomm,15(41),8320-8329.
MLA	Yi FY,et al."Construction of porous Mn(II)-based metal-organic frameworks by flexible hexacarboxylic acid and rigid coligands".crystengcomm 15.41(2013):8320-8329.