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Microstructure and Physical Properties of Two Charge Density Wave States in NbSe3 Nanowires
Shi, HL ; Yang, HX ; Tian, HF ; Wang, ZW ; Qin, YB ; Song, YJ ; Luo, MT ; Wang, WZ ; Li, JQ
刊名JOURNAL OF NANOSCIENCE AND NANOTECHNOLOGY
2013
卷号13期号:6页码:4123
关键词Niobium Triselenide Nanowires CDW Incommensurate Modulation Nonlinear Effect HRTEM Electron Diffraction
ISSN号1533-4880
通讯作者Shi, HL (reprint author), Minzu Univ China, Sch Sci, Beijing 100081, Peoples R China.
中文摘要The whisker-like niobium triselenide (NbSe3) nanowires were synthesized using the traditional solid state reaction. X-ray diffraction experiment suggested the monoclinic structure (P2(1)/m), and crystal morphology analysis indicated that the band-like shape is the stable morphology. Two charge density wave (CDW) states were observed at around 140 K and 50 K, respectively, and the nonlinear effect was detected in the CDW states from the R-T and I-V measurements. The doped Fe atoms, as pinning centers, play an important role in the nonlinear properties of the CDW state. Electron diffraction and HRTEM experiments were carried out at different temperatures in order to investigate the structural features and their evolution. The sets of incommensurate modulation spots with modulation vector q(1) similar to (h, k 0.243, I) appeared below 145 K, and other sets of complex superstructure spots with modulation vector q(2) similar to (h, k + 0.3, I + 1.3424), q(3) similar to (h, k-0.3137, 1.5685), = (1/3, k, 1) and q(5) = (0.5, 0.25, 0.5) were observed at [1 0 0] and [3 0 1] zone axis at about 20 K, respectively, suggesting the complex inconnmensurately modulated structures in this material.
资助信息National Science Foundation of China; Knowledge Innovation Project of the Chinese Academy of Sciences; 973 Projects of the Ministry of Science and Technology of China; 985 Project [98507010009]; 211 Project of Ministry of Education of China; Undergraduate Research and Training Program [URTP2012110036]
语种英语
公开日期2014-01-16
内容类型期刊论文
源URL[http://ir.iphy.ac.cn/handle/311004/57217]  
专题物理研究所_物理所公开发表论文_物理所公开发表论文_期刊论文
推荐引用方式
GB/T 7714
Shi, HL,Yang, HX,Tian, HF,et al. Microstructure and Physical Properties of Two Charge Density Wave States in NbSe3 Nanowires[J]. JOURNAL OF NANOSCIENCE AND NANOTECHNOLOGY,2013,13(6):4123.
APA Shi, HL.,Yang, HX.,Tian, HF.,Wang, ZW.,Qin, YB.,...&Li, JQ.(2013).Microstructure and Physical Properties of Two Charge Density Wave States in NbSe3 Nanowires.JOURNAL OF NANOSCIENCE AND NANOTECHNOLOGY,13(6),4123.
MLA Shi, HL,et al."Microstructure and Physical Properties of Two Charge Density Wave States in NbSe3 Nanowires".JOURNAL OF NANOSCIENCE AND NANOTECHNOLOGY 13.6(2013):4123.
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