Synthesis and magnetic property of condensation product of bis(oxamide oximato)nickel and 1,1 '-dicarbaldehydeferrocene

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	Synthesis and magnetic property of condensation product of bis(oxamide oximato)nickel and 1,1 '-dicarbaldehydeferrocene
	Ji, TH ; Zhao, JG ; Wen, GH ; Shen, BG ; Zhan, WS
刊名	JOURNAL OF APPLIED PHYSICS
	1999
卷号	85 期号:8 页码:5702
关键词	NITRONYL NITROXIDE DESIGN MANGANESE(II) COMPLEXES CHAINS
ISSN号	0021-8979
通讯作者	Ji, TH (reprint author), Chinese Acad Sci, Inst Phys, State Key Lab Magnetism, POB 603, Beijing 100080, Peoples R China.
中文摘要	A new multinuclear metals condensation product (polymer C) was prepared by a condensation reaction between bis(oxamide oximato)nickel and 1,1'-dicarbaldehydeferrocene. Its structure was investigated by using elemental analysis, Fourier-transform infared, x-ray diffraction, and thermogravimetric analysis techniques. All these results show that the polymer is a three-dimensional layer, large pi-conjugated part order structure and its initial decomposition temperature is about 230 degrees C. The magnetic susceptibility was measured from 5 to 160 K by a superconducting quantum interference device magnetometer under the applied magnetic field of 10 kOe. The plot of 1/chi(M) vs T is linear in the range of 5-30 K, but deviates from the line above 30 K. The Weiss constant theta calculated according to the equation chi(M)=C/(T-theta) in the 5-30 K was -2.1 K, indicating presence of a weak antiferromagnetic coupling between the most near neighboring two metal ions. The polymer C can also easily complex with metal ion Cu2+, but is difficult with Mn2+. (C) 1999 American Institute of Physics. [S0021-8979(99)22608-4].
收录类别	SCI
语种	英语
公开日期	2013-09-24
内容类型	期刊论文
源URL	[http://ir.iphy.ac.cn/handle/311004/54364]
专题	物理研究所_物理所公开发表论文_物理所公开发表论文_期刊论文
推荐引用方式 GB/T 7714	Ji, TH,Zhao, JG,Wen, GH,et al. Synthesis and magnetic property of condensation product of bis(oxamide oximato)nickel and 1,1 '-dicarbaldehydeferrocene[J]. JOURNAL OF APPLIED PHYSICS,1999,85(8):5702.
APA	Ji, TH,Zhao, JG,Wen, GH,Shen, BG,&Zhan, WS.(1999).Synthesis and magnetic property of condensation product of bis(oxamide oximato)nickel and 1,1 '-dicarbaldehydeferrocene.JOURNAL OF APPLIED PHYSICS,85(8),5702.
MLA	Ji, TH,et al."Synthesis and magnetic property of condensation product of bis(oxamide oximato)nickel and 1,1 '-dicarbaldehydeferrocene".JOURNAL OF APPLIED PHYSICS 85.8(1999):5702.