Homogeneous Preparation of Cellulose Acetate Propionate (CAP) and Cellulose Acetate Butyrate (CAB) from Sugarcane Bagasse Cellulose in Ionic Liquid
Huang, Kelin2,3,7; Wang, Ben1,3; Cao, Yan1; Li, Huiquan1; Wang, Jinshu2; Lin, Weijiang4; Mu, Chaoshi5; Liao, Dankui6
刊名JOURNAL OF AGRICULTURAL AND FOOD CHEMISTRY
2011-05-25
卷号59期号:10页码:5376-5381
关键词AmimCl ionic liquid sugarcane bagasse cellulose cellulose acetate butyrate cellulose acetate propionate recycling
ISSN号0021-8561
其他题名J. Agric. Food Chem.
中文摘要Cellulose acetate butyrate (CAB) and cellulose acetate propionate (CAP) were prepared homogeneously in a 1-allyl-3-methylimidazolium chloride (AmimCl) ionic liquid system from sugarcane bagasse (SB). The reaction temperature, reaction time, and molar ratio of butyric (propionic) anhydride/anhydroglucose units in the cellulose affect the butyryl (B) or propionyl (P) content of CAB or CAP samples. The (13)C NMR data revealed the distribution of the substituents of CAB and CAP. The thermal stability of sugar cane bagasse cellulose was found by thermogravimetric analysis to have decreased after chemical modification. After reaction, the ionic liquid was effectively recycled and reused. This study provides a new way for high-value-added utilization of SB and realizing the objective of turning waste into wealth.
英文摘要Cellulose acetate butyrate (CAB) and cellulose acetate propionate (CAP) were prepared homogeneously in a 1-allyl-3-methylimidazolium chloride (AmimCl) ionic liquid system from sugarcane bagasse (SB). The reaction temperature, reaction time, and molar ratio of butyric (propionic) anhydride/anhydroglucose units in the cellulose affect the butyryl (B) or propionyl (P) content of CAB or CAP samples. The (13)C NMR data revealed the distribution of the substituents of CAB and CAP. The thermal stability of sugar cane bagasse cellulose was found by thermogravimetric analysis to have decreased after chemical modification. After reaction, the ionic liquid was effectively recycled and reused. This study provides a new way for high-value-added utilization of SB and realizing the objective of turning waste into wealth.
WOS标题词Science & Technology ; Life Sciences & Biomedicine ; Physical Sciences
类目[WOS]Agriculture, Multidisciplinary ; Chemistry, Applied ; Food Science & Technology
研究领域[WOS]Agriculture ; Chemistry ; Food Science & Technology
关键词[WOS]ACETYLATION ; CHLORIDE ; SOLVENT
收录类别SCI
原文出处://WOS:000290691300027
语种英语
WOS记录号WOS:000290691300027
公开日期2013-11-28
内容类型期刊论文
版本出版稿
源URL[http://ir.ipe.ac.cn/handle/122111/6365]  
专题过程工程研究所_研究所(批量导入)
作者单位1.Chinese Acad Sci, Inst Proc Engn, Beijing 100190, Peoples R China
2.Beijing Univ Technol, Sch Mat Sci & Engn, Beijing 100124, Peoples R China
3.Guangxi Chem & Ind Res Inst, Nanning 530004, Guangxi, Peoples R China
4.Guangxi Sci & Technol Dept, Nanning 530002, Guangxi, Peoples R China
5.Guangxi Sci & Technol Informat Res Inst, Nanning 530002, Guangxi, Peoples R China
6.Guangxi Univ, Sch Chem & Chem Engn, Nanning 530004, Guangxi, Peoples R China
7.China Acad Sci & Technol Dev, Guangxi Branch, Nanning 530022, Guangxi, Peoples R China
推荐引用方式
GB/T 7714
Huang, Kelin,Wang, Ben,Cao, Yan,et al. Homogeneous Preparation of Cellulose Acetate Propionate (CAP) and Cellulose Acetate Butyrate (CAB) from Sugarcane Bagasse Cellulose in Ionic Liquid[J]. JOURNAL OF AGRICULTURAL AND FOOD CHEMISTRY,2011,59(10):5376-5381.
APA Huang, Kelin.,Wang, Ben.,Cao, Yan.,Li, Huiquan.,Wang, Jinshu.,...&Liao, Dankui.(2011).Homogeneous Preparation of Cellulose Acetate Propionate (CAP) and Cellulose Acetate Butyrate (CAB) from Sugarcane Bagasse Cellulose in Ionic Liquid.JOURNAL OF AGRICULTURAL AND FOOD CHEMISTRY,59(10),5376-5381.
MLA Huang, Kelin,et al."Homogeneous Preparation of Cellulose Acetate Propionate (CAP) and Cellulose Acetate Butyrate (CAB) from Sugarcane Bagasse Cellulose in Ionic Liquid".JOURNAL OF AGRICULTURAL AND FOOD CHEMISTRY 59.10(2011):5376-5381.
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