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	Facile Solvothermal Synthesis of Porous Cubic Cu Microparticles as Copper Catalysts for Rochow Reaction
	Zhang, Zailei1,2; Che, Hongwei1; Wang, Yingli1; She, Xilin2; Sun, Jin2; Gunawan, Poernomo3; Zhong, Ziyi3; Su, Fabing1
刊名	ACS APPLIED MATERIALS & INTERFACES
	2012-03-01
卷号	4期号:3页码:1295-1302
关键词	porous cubic Cu microparticles solvothermal method copper catalysts Rochow reaction
ISSN号	1944-8244
其他题名	ACS Appl. Mater. Interfaces
中文摘要	Porous cubic Cu microparticles were synthesized by a facile solvothermal method using Cu(CH3COO)(2)center dot H2O as the Cu precursor and NaOH in a solution containing ethanol, ethylene glycol, and water. The synthesis conditions were investigated and a growth process of porous cubic Cu microparticles was proposed. The catalytic properties of the porous Cu microparticles as model copper catalysts for Rochow reaction were explored. The samples were characterized by X-ray diffraction, scanning electron microscopy, transmission electron microscopy, thermogravimetric analysis, temperature-programmed reduction, and nitrogen adsorption. It was found that the morphology and structure of the porous cubic Cu microparticles are highly dependent on the reaction time and temperature as well as on the amount of reactants added. Compared to the commercial Cu microparticles with irregular morphology and dense internal structure, porous cubic Cu microparticles show much higher dimethyldichlorosilane selectivity and Si conversion via Rochow reaction, which are attributed to the enhanced formation of active CuxSi phase and gas transportation in the presence of the pore system within microparticles, demonstrating the significance of the pore structure of the copper catalysts in catalytic reactions of organosilane synthesis.
英文摘要	Porous cubic Cu microparticles were synthesized by a facile solvothermal method using Cu(CH3COO)(2)center dot H2O as the Cu precursor and NaOH in a solution containing ethanol, ethylene glycol, and water. The synthesis conditions were investigated and a growth process of porous cubic Cu microparticles was proposed. The catalytic properties of the porous Cu microparticles as model copper catalysts for Rochow reaction were explored. The samples were characterized by X-ray diffraction, scanning electron microscopy, transmission electron microscopy, thermogravimetric analysis, temperature-programmed reduction, and nitrogen adsorption. It was found that the morphology and structure of the porous cubic Cu microparticles are highly dependent on the reaction time and temperature as well as on the amount of reactants added. Compared to the commercial Cu microparticles with irregular morphology and dense internal structure, porous cubic Cu microparticles show much higher dimethyldichlorosilane selectivity and Si conversion via Rochow reaction, which are attributed to the enhanced formation of active CuxSi phase and gas transportation in the presence of the pore system within microparticles, demonstrating the significance of the pore structure of the copper catalysts in catalytic reactions of organosilane synthesis.
WOS标题词	Science & Technology ; Technology
类目[WOS]	Nanoscience & Nanotechnology ; Materials Science, Multidisciplinary
研究领域[WOS]	Science & Technology - Other Topics ; Materials Science
关键词[WOS]	SHAPE-CONTROLLED SYNTHESIS ; DIMETHYLDICHLOROSILANE SYNTHESIS ; HYDROTHERMAL ROUTE ; REDUCTION ROUTE ; ONE-STEP ; METHYLCHLOROSILANES ; SILICON ; GOLD ; NANOPARTICLES ; ADSORPTION
收录类别	SCI
原文出处	://WOS:000301968400024
语种	英语
WOS记录号	WOS:000301968400024
公开日期	2013-11-28
内容类型	期刊论文
版本	出版稿
源URL	[http://ir.ipe.ac.cn/handle/122111/6342]
专题	过程工程研究所_研究所（批量导入）
作者单位	1.Chinese Acad Sci, Inst Proc Engn, State Key Lab Multiphase Complex Syst, Beijing 100190, Peoples R China 2.Qingdao Univ, Coll Chem & Environm Engn, Qingdao 266071, Peoples R China 3.ASTAR, Inst Chem Engn & Sci, Jurong Isl 627833, Singapore
推荐引用方式 GB/T 7714	Zhang, Zailei,Che, Hongwei,Wang, Yingli,et al. Facile Solvothermal Synthesis of Porous Cubic Cu Microparticles as Copper Catalysts for Rochow Reaction[J]. ACS APPLIED MATERIALS & INTERFACES,2012,4(3):1295-1302.
APA	Zhang, Zailei.,Che, Hongwei.,Wang, Yingli.,She, Xilin.,Sun, Jin.,...&Su, Fabing.(2012).Facile Solvothermal Synthesis of Porous Cubic Cu Microparticles as Copper Catalysts for Rochow Reaction.ACS APPLIED MATERIALS & INTERFACES,4(3),1295-1302.
MLA	Zhang, Zailei,et al."Facile Solvothermal Synthesis of Porous Cubic Cu Microparticles as Copper Catalysts for Rochow Reaction".ACS APPLIED MATERIALS & INTERFACES 4.3(2012):1295-1302.

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