Reactivity of Dialumane and "Dialumene" Compounds toward Alkenes

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	Reactivity of Dialumane and "Dialumene" Compounds toward Alkenes
	Zhao YX(赵艳霞)1,3; Lei YB(雷一波)2; Dong QS(董青松)1,3; Wu B(吴彪)2; Yang XJ(杨晓娟)1,2
刊名	Chemistry - A European Journal
	2013
卷号	19 期号:36 页码:12059-12066
关键词	alkenes aluminum cycloaddition insertion reaction mechanisms
ISSN号	0947-6539
通讯作者	杨晓娟
英文摘要	The reactions of dialumane [L(thf)Al-Al (thf)L] (1, L=[{(2,6- iPr₂C₆H₃)NC(Me)}₂]^2_) with stilbene and styrene afforded the oxidation/insertion products [L(thf)Al(CH(Ph)-CH(Ph))AlL] (2) and [L(thf)Al(CH(Ph)-CH₂)Al(thf)L] (3), respectively. In the presence of Na metal, precursor 1 reacted with butadienes, possibly through the reduced “dialumene” or the “carbene-like” :AlL species, to yield aluminacyclopentenes [LAl(CH₂C(Me)=C(Me)CH₂)Na]_n (4a) and [Na(dme)₃][LAl(CH₂C(Me)=CHCH₂)] (4b, dme=dimethoxyethane) as [1+4] cycloaddition products, as well as the [2+4] cycloaddition product 1,6-dialumina-3,8-cyclodecadiene, [{Na-(dme)}₂][LAl(CH₂C(Me)=C(Me)-CH₂)₂AlL] (5). The possible mechanisms of the cycloaddition reactions were studied by using DFT computations.
学科主题	物理化学与绿色催化
收录类别	SCI
资助信息	the National Natural Science Foundation of China (20972169;21273170)
语种	英语
WOS记录号	WOS:000323514600035
公开日期	2013-12-16
内容类型	期刊论文
源URL	[http://210.77.64.217/handle/362003/4719]
专题	兰州化学物理研究所_OSSO国家重点实验室兰州化学物理研究所_ERC国家工程研究中心
作者单位	1.Chinese Acad Sci, Lanzhou Inst Chem Phys, State Key Lab Oxo Synth & Select Oxidat, Lanzhou 730000, Peoples R China 2.NW Univ Xian, Coll Chem & Mat Sci, Xian 710069, Peoples R China 3.Chinese Acad Sci, Grad Univ, Beijing 100049, Peoples R China
推荐引用方式 GB/T 7714	Zhao YX,Lei YB,Dong QS,et al. Reactivity of Dialumane and "Dialumene" Compounds toward Alkenes[J]. Chemistry - A European Journal,2013,19(36):12059-12066.
APA	Zhao YX,Lei YB,Dong QS,Wu B,&Yang XJ.(2013).Reactivity of Dialumane and "Dialumene" Compounds toward Alkenes.Chemistry - A European Journal,19(36),12059-12066.
MLA	Zhao YX,et al."Reactivity of Dialumane and "Dialumene" Compounds toward Alkenes".Chemistry - A European Journal 19.36(2013):12059-12066.