Tuning the interfacial hole injection barrier between p-type organic materials and Co using a MoO3 buffer layer
Wang, YZ ; Cao, L ; Qi, DC ; Chen, W ; Wee, ATS ; Gao, XY(高兴宇)
刊名JOURNAL OF APPLIED PHYSICS
2012
卷号112期号:3
ISSN号0021-8979
英文摘要We demonstrate that the interfacial hole injection barrier Delta(h) between p-type organic materials (i.e., CuPc and pentacene) and Co substrate can be tuned by the insertion of a MoO3 buffer layer. Using ultraviolet photoemission spectroscopy, it was found that the introduction of MoO3 buffer layer effectively reduces the hole injection barrier from 0.8 eV to 0.4 eV for the CuPc/Co interface, and from 1.0 eV to 0.4 eV for the pentacene/Co interface, respectively. In addition, by varying the thickness of the buffer, the tuning effect of Delta(h) is shown to be independent of the thickness of MoO3 interlayer at both CuPc/Co and pentacene/Co interfaces. This Fermi level pinning effect can be explained by the integer charge-transfer model. Therefore, the MoO3 buffer layer has the potential to be applied in p-type organic spin valve devices to improve the device performance via reducing the interfacial hole injection barrier. (C) 2012 American Institute of Physics. [http://dx.doi.org/10.1063/1.4740455]
语种英语
WOS记录号WOS:000308335400047
公开日期2013-12-05
内容类型期刊论文
源URL[http://ir.sinap.ac.cn/handle/331007/13330]  
专题上海应用物理研究所_中科院上海应用物理研究所2011-2017年
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GB/T 7714
Wang, YZ,Cao, L,Qi, DC,et al. Tuning the interfacial hole injection barrier between p-type organic materials and Co using a MoO3 buffer layer[J]. JOURNAL OF APPLIED PHYSICS,2012,112(3).
APA Wang, YZ,Cao, L,Qi, DC,Chen, W,Wee, ATS,&Gao, XY.(2012).Tuning the interfacial hole injection barrier between p-type organic materials and Co using a MoO3 buffer layer.JOURNAL OF APPLIED PHYSICS,112(3).
MLA Wang, YZ,et al."Tuning the interfacial hole injection barrier between p-type organic materials and Co using a MoO3 buffer layer".JOURNAL OF APPLIED PHYSICS 112.3(2012).
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