Green and facile synthesis of carbon nanotube supported Pd nanoparticle catalysts and their application in the hydrogenation of nitrobenzene

CORC > 兰州化学物理研究所 > 中国科学院兰州化学物理研究所 > OSSO国家重点实验室

	Green and facile synthesis of carbon nanotube supported Pd nanoparticle catalysts and their application in the hydrogenation of nitrobenzene
	Wang ZL(王仲来)1,2 ; Liu H(刘华)1,2; Chen L(陈龙)1; Chou LJ(丑凌军)1 ; Wang XL(王晓来)1 ; Wang XL(王晓来)
刊名	Journal of Materials Research
	2013
卷号	28 期号:10 页码:1326-1333
ISSN号	0884-2914
通讯作者	王晓来
英文摘要	Carbon nanotubes (CNTs) supported Pd nanoparticle (NP) catalysts (Pd/CNTs) were prepared by a green and facile synthesis method based on hydrogen-bonding self-assembly. The size and loading of Pd NPs on catalysts were easily controlled by tuning both the relative amount of citrate to Pd salt in the solution and the relative amount of Pd NPs to CNTs. The size of Pd NPs on as-prepared catalysts can be tuned in the range of 3-6 nm, and Pd loading can be controlled in the range of 0-19 wt%. The catalysts were characterized by Brunauer-Emmett-Teller measurement, x-ray diffraction spectroscopy, and x-ray photoelectron spectroscopy. The performance of Pd/CNTs catalysts was evaluated in the hydrogenation of nitrobenzene. Compared with the catalysts prepared by the impregnation method or supported on conventional supports, Pd/CNTs catalysts show relatively higher activity and selectivity. The recyclability tests indicate that the Pd/CNTs catalysts can be used at least five times without significant loss in activity and selectivity.
学科主题	物理化学与绿色催化
收录类别	SCI
语种	英语
WOS记录号	WOS:000319000800007
公开日期	2013-12-04
内容类型	期刊论文
源URL	[http://210.77.64.217/handle/362003/4403]
专题	兰州化学物理研究所_OSSO国家重点实验室
通讯作者	Wang XL(王晓来)
作者单位	1.Chinese Acad Sci, Lanzhou Inst Chem Phys, State Key Lab Oxo Synth & Select Oxidat, Lanzhou 730000, Peoples R China 2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China
推荐引用方式 GB/T 7714	Wang ZL,Liu H,Chen L,et al. Green and facile synthesis of carbon nanotube supported Pd nanoparticle catalysts and their application in the hydrogenation of nitrobenzene[J]. Journal of Materials Research,2013,28(10):1326-1333.
APA	Wang ZL,Liu H,Chen L,Chou LJ,Wang XL,&王晓来.(2013).Green and facile synthesis of carbon nanotube supported Pd nanoparticle catalysts and their application in the hydrogenation of nitrobenzene.Journal of Materials Research,28(10),1326-1333.
MLA	Wang ZL,et al."Green and facile synthesis of carbon nanotube supported Pd nanoparticle catalysts and their application in the hydrogenation of nitrobenzene".Journal of Materials Research 28.10(2013):1326-1333.