Waterborne superhydrophobic coating with abrasion and corrosion resistant capabilities
Yang, Guang1,2,3,4; Zhang, Binbin3,4; Zheng, Chuanbo1,2; Xu, Weichen3,4; Hou, Baorong3,4
刊名COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS
2023-05-05
卷号664页码:12
关键词Superhydrophobic Corrosion Robust Durability Stability G Yang et al
ISSN号0927-7757
DOI10.1016/j.colsurfa.2023.131170
通讯作者Zhang, Binbin(zhangbinbin11@mails.ucas.ac.cn) ; Zheng, Chuanbo(15952802516@139.com)
英文摘要Superhydrophobic materials have been extensively exploited for corrosion protection because of their unique non-wetting properties, but restricted by the complicated fabrication process, fluorinated chemicals usage, weak interfacial binding force, low hardness, and poor abrasion/scratch resistance. In this paper, we designed a waterborne superhydrophobic coating based on modified Al2O3 nanoparticles (M-Al2O3) and waterborne epoxy resin through a versatile spray-coating approach. When the mass ratio of epoxy/M-Al2O3 was 1.5, the coating features both superhydrophobic properties (water contact angle -150.8 +/- 0.6 degrees and sliding angle -4.9 +/- 0.2 degrees) and optimal abrasion-resistant stability. The coating can maintain its water-repellent superhydrophobicity after 90 abrasion cycles and 120 tape-peeling cycles, indicating reinforced interfacial robustness. Moreover, the coating exhibits excellent self-cleaning, anti-fouling, and corrosion-resistant behaviors with greatly enhanced charge transfer resistance (Rct) and lowest frequency impedance values (|Z|0.01Hz). The corrosion inhibition ef-ficiency of the original coating, coating after 90 abrasion cycles and coating after 120 tape-peeling cycles were 99.99 %, 97.54 %, and 97.52 % respectively, confirming a durable anti-corrosion stability. In addition, the coating retains its superhydrophobic properties after a 6 H pencil hardness test and knife scratch test, which demonstrates its robustness and stability against mechanical damage.
资助项目Shandong Provincial Natural Science Foundation[ZR2022YQ35] ; Shandong Provincial Natural Science Foundation[ZR2021LFG004] ; Youth Innovation Promotion Association of Chi- nese Academy of Sciences[2021207] ; Wenhai Program of the S & T Fund of Shandong Province for Pilot National Laboratory for Marine Science and Technology (Qingdao)[2021WHZZB2304]
WOS关键词MARINE CORROSION ; SURFACES ; FABRICATION ; BARRIER
WOS研究方向Chemistry
语种英语
出版者ELSEVIER
WOS记录号WOS:001006940800001
内容类型期刊论文
源URL[http://ir.qdio.ac.cn/handle/337002/182249]  
专题海洋研究所_海洋腐蚀与防护研究发展中心
通讯作者Zhang, Binbin; Zheng, Chuanbo
作者单位1.Jiangsu Univ Sci & Technol, Sch Mat Sci & Engn, Zhenjiang 212003, Peoples R China
2.Jiangsu Univ Sci & Technol, Sch Met Engn, Zhangjiagang 215600, Peoples R China
3.Chinese Acad Sci, Inst Oceanol, CAS Key Lab Marine Environm Corros & Biofouling, Qingdao 266071, Peoples R China
4.Pilot Natl Lab Marine Sci & Technol Qingdao, Open Studio Marine Corros & Protect, Qingdao 266237, Peoples R China
推荐引用方式
GB/T 7714
Yang, Guang,Zhang, Binbin,Zheng, Chuanbo,et al. Waterborne superhydrophobic coating with abrasion and corrosion resistant capabilities[J]. COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS,2023,664:12.
APA Yang, Guang,Zhang, Binbin,Zheng, Chuanbo,Xu, Weichen,&Hou, Baorong.(2023).Waterborne superhydrophobic coating with abrasion and corrosion resistant capabilities.COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS,664,12.
MLA Yang, Guang,et al."Waterborne superhydrophobic coating with abrasion and corrosion resistant capabilities".COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS 664(2023):12.
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